Chinese Journal of Organic Chemistry ›› 2022, Vol. 42 ›› Issue (8): 2542-2550.DOI: 10.6023/cjoc202201015 Previous Articles     Next Articles

Special Issue: 二氧化碳虚拟合辑



徐勇a,b, 张永兴a,b, 胡佳a,b, 陈宬a, 原晔a,*(), Francis Verpoorta,b,*()   

  1. a 武汉理工大学材料复合新技术国家重点实验室 武汉 430070
    b 武汉理工大学材料科学与工程学院 武汉 430070
  • 收稿日期:2022-01-11 修回日期:2022-04-02 发布日期:2022-09-06
  • 通讯作者: 原晔, Francis Verpoort
  • 作者简介:
  • 基金资助:
    国家自然科学基金(22102127); 国家自然科学基金(21950410754); 齐鲁工业大学(山东省科学院)生物基材料与绿色造纸国家重点实验室开放基金(GZKF202023); 催化转化与能源材料化学教育部重点实验室暨催化材料科学湖北省重点实验室开放基金(CHCL19002)

Synthesis of β-Oxopropylcarbamates Catalyzed by ZnO/Ionic Liquids under Atmospheric CO2

Yong Xua,b, Yongxing Zhanga,b, Jia Hua,b, Cheng Chena, Ye Yuana(), Francis Verpoorta,b()   

  1. a State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070
    b School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070
  • Received:2022-01-11 Revised:2022-04-02 Published:2022-09-06
  • Contact: Ye Yuan, Francis Verpoort
  • About author:
    These authors contributed equally to this work.
  • Supported by:
    National Natural Science Foundation of China(22102127); National Natural Science Foundation of China(21950410754); State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences(GZKF202023); Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education ;Hubei Key Laboratory of Catalysis and Materials Science(CHCL19002)

Carbamate compounds exhibit a broad applicable scope in medicine, pesticide, resin modification, fabric finishing and organic synthesis. A methodology using ZnO/ionic liquids as the catalyst for the three-component coupling reactions of carbon dioxide (CO2), secondary amines and propargylic alcohols to produce various β-oxopropylcarbamates was developed. This catalytic system exhibited robust recyclability and broad substrate scope. Moreover, it showed considerable catalytic activity under atmospheric CO2, indicating its potential in carbon capture and utilization processes.

Key words: carbon dioxide, β-oxopropylcarbamate, ionic liquid, zinc oxide, three component reaction