Recent Advance of Amino-acids and Their Derivatives as Chiral Ligands in Asymmetric Transfer Hydrogenation of Ketones

doi:10.6023/cjoc1104231

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (01): 19-29.DOI: 10.6023/cjoc1104231 Previous Articles Next Articles

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手性氨基酸及其衍生物配体在酮不对称氢转移反应中的应用进展

李小娜, 张鹏亮, 段凯, 王家喜

河北工业大学化工学院天津 300130

收稿日期:2011-04-23 修回日期:2011-06-10 发布日期:2011-08-24
通讯作者: 王家喜 E-mail:jwang252004@126.COM
基金资助:
河北省自然科学基金(No. B2011202087)资助项目.

Recent Advance of Amino-acids and Their Derivatives as Chiral Ligands in Asymmetric Transfer Hydrogenation of Ketones

Li Xiaona, Zhang Pengliang, Duan Kai, Wang Jiaxi

School of Chemical Engineering, Hebei University of Technology, Tianjin 300130

Received:2011-04-23 Revised:2011-06-10 Published:2011-08-24
Contact: WANG Jia-Xi E-mail:jwang252004@126.COM
Supported by:
Project supported by the Natural Science Foundation of Hebei Province (No. B2011202087).

The asymmetric transfer hydrogenation (ATH) reaction of prochiral ketones is an important method to produce chiral alcohols. Recently, the application of chiral amino acids and their derivatives as ligands in ATH of prochiral ketones promoted by the ruthenium, rhodium or iridium complexes have been attracted more attentions. Herein the catalytic properties of amino acids, amino acid based amides, thioamides, hydroxamic acids, hydrazides, amino alcohols and hydroxy amides as ligands in the ruthenium, rhodium or iridium catalyzed ATH of prochiral ketones have been overviewed.

Key words: chiral amino acid, derivative of amino acid, metal complex of amino acid, asymmetric transfer hydrogenation

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Li Xiaona, Zhang Pengliang, Duan Kai, Wang Jiaxi . Recent Advance of Amino-acids and Their Derivatives as Chiral Ligands in Asymmetric Transfer Hydrogenation of Ketones[J]. Chin. J. Org. Chem., 2012, 32(01): 19-29.

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手性氨基酸及其衍生物配体在酮不对称氢转移反应中的应用进展

Recent Advance of Amino-acids and Their Derivatives as Chiral Ligands in Asymmetric Transfer Hydrogenation of Ketones

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