Recent Progress in Asymmetric Synthesis of Kabachnik-Fields Reaction

doi:10.6023/cjoc114224

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (01): 13-18.DOI: 10.6023/cjoc114224 Previous Articles Next Articles

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不对称Kabachnik-Fields 反应合成研究进展

万德慧, 吴明书, 马静雅

海南师范大学化学与化工学院热带药用植物化学省部共建重点实验室海口 570000

收稿日期:2011-04-22 修回日期:2011-08-15 发布日期:2011-09-05
通讯作者: 万德慧 E-mail:wdhfsh@163.com
基金资助:
国家自然科学基金(No. 21162008)资助项目.

Recent Progress in Asymmetric Synthesis of Kabachnik-Fields Reaction

Wan Dehui, Wu Mingshu, Ma Jingya

Key Laboratory of Tropical Medicinal Plant Chemistry of the Ministry of Education and Hainan Province, College of Chemistry & Chemical Engineering, Hainan Normal University, Haikou 571158

Received:2011-04-22 Revised:2011-08-15 Published:2011-09-05
Contact: DeHui WAN E-mail:wdhfsh@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21162008).

Asymmetric three-component Kabachnik-Field reaction for the stereoselective synthesis of optically active α-amino phosphonates has been received considerable attention due to their great intrinsic advantages as well as their applications in drug discovery. This review covers recent progress on asymmetric three-component Kabachnik-Field reaction including the chiral catalysts and optical active substrate induction approaches to chiral α-aminoalkylphosphonic acid derivatives. The influence of the chiral catalysts and reaction substrate configuration on the reaction stereoselectivity is the major focus. It elicits issues and perspectives of asymmetric three-component Kabachnik-Field reaction in the end.

Key words: Kabachnik-Fields reaction, asymmetric synthesis, chiral α-aminoalkylphosphonic acid

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Wan Dehui, Wu Mingshu, Ma Jingya . Recent Progress in Asymmetric Synthesis of Kabachnik-Fields Reaction[J]. Chin. J. Org. Chem., 2012, 32(01): 13-18.

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不对称Kabachnik-Fields 反应合成研究进展

Recent Progress in Asymmetric Synthesis of Kabachnik-Fields Reaction

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