Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative

doi:10.6023/cjoc1107262

Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (05): 953-956.DOI: 10.6023/cjoc1107262 Previous Articles Next Articles

Notes

新型萘基修饰四硫富瓦烯衍生物的合成及性质研究

赵邦屯^a, 刘连委^b, 李晓川^b, 渠桂荣^b

a 洛阳师范学院化学系洛阳 471022;
b 河南师范大学化学与环境科学学院新乡 453007

收稿日期:2011-06-26 修回日期:2011-12-25 发布日期:2012-01-06
通讯作者: 赵邦屯, 渠桂荣 E-mail:zbt@lynu.edu.cn; quguir@sina.com
基金资助:
国家自然科学基金(Nos. 20872058, 21172105)资助项目.

Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative

Zhao Bangtun^a, Liu Lianwei^b, Li Xiaochuan^b, Qu Guirong^b

a Department of Chemistry, Luoyang Normal University, Luoyang 471022;
b College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007

Received:2011-06-26 Revised:2011-12-25 Published:2012-01-06
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 20872058, 21172105).

A novel naphthol-substituted tetrathiafulvalene derivative 2 was conveniently synthesized and characterized by ¹H NMR, ¹³C NMR, IR, MS techniques and elemental analysis. The recognition properties for 2 were carried out by CV (cyclic voltammetry) and fluorescence titration methods. The CV experiments show that compound 2 has apparent response to Zn²⁺ and Cd²⁺. Fluorescence titration experiments indicate that the fluorescence emission intensity of 2 has increased while the detected ions were added independently. Especially, while Zn²⁺ or Cd²⁺ was added, the fluorescence enhancement was more notable. Therefore, the compound 2 could serve as a dual optical-electrochemical chemosensor for Zn²⁺ and Cd²⁺ ions.

Key words: tetrathiafulvalene, naphthalene thiol, ions recognition

Cite this article

Zhao Bangtun, Liu Lianwei, Li Xiaochuan, Qu Guirong. Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative[J]. Chin. J. Org. Chem., 2012, 32(05): 953-956.

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新型萘基修饰四硫富瓦烯衍生物的合成及性质研究

Synthesis and Properties of A Novel Naphthol-Substituted Tetrathiafulvalene Derivative

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