Research Progress in the Construction of Aromatic C—N Bond from Activation of Aromatic C—H Bond

doi:10.6023/cjoc1108122

Abstract

Amines are important compounds that are found throughout the pharmaceutical, bioactive natural products and agrochemical industries. The transformation from aromatic C—H bond to aromatic C—N bond is an important organic conversion. It is an effective method for the construction of aromatic amine. This transformation has the characteristic of atom economy, sustainable development and environment friendly. This review is focused on the research progress in the direct amination of C—H bonds in the past decade.

Key words: activation of aromatic C—H bond, amination, aromatic amine, nitrene insertion, oxidative amination

Cite this article

Xu Juan, Wei Zhen, Li Jiarong. Research Progress in the Construction of Aromatic C—N Bond from Activation of Aromatic C—H Bond[J]. Chin. J. Org. Chem., 2012, 32(07): 1208-1216.

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直接活化芳香C—H 键构建芳香C—N 键的研究进展