Cesium Chloride Catalysized the Reaction of Sodium (Potassium) Carboxylates with Alkyl Bromides (Chlorides)

doi:10.6023/cjoc201208010

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (01): 190-194.DOI: 10.6023/cjoc201208010 Previous Articles Next Articles

Notes

氯化铯催化羧酸钠(钾)与α-氯代乙酸酯及溴(氯)代烃反应

刘文奇^a, 奇建永^b, 陈锦杨^b, 李宁波^b, 邱仁华^b, 许新华^b

a 湘南学院湘南稀贵金属化合物及其应用湖南省重点实验郴州 423000;
b 湖南大学化学化工学院长沙 410082

收稿日期:2012-08-13 修回日期:2012-09-08 发布日期:2012-09-21
通讯作者: 许新华 E-mail:xhx1581@yahoo.com.cn
基金资助:
湖南省自然科学基金(No. 08JJ3018)资助项目.

Cesium Chloride Catalysized the Reaction of Sodium (Potassium) Carboxylates with Alkyl Bromides (Chlorides)

Liu Wenqi^a, Qi Jianyong^b, Chen Jinyang^b, Li Ningbo^b, Qui Renhua^b, Xu Xinhua^b

a Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds Research and Application, Xiangnan University, Chenzhou 42300;
b College of Chemistry Chemical and Engineering, Hunan University, Changsha 410082

Received:2012-08-13 Revised:2012-09-08 Published:2012-09-21
Supported by:
Project supported by the Natural Science Foundation of Hunan Province (No. 08JJ3018).

In the presence of catalytic amounts of cesium chloride, using DMF as solvent, sodium (potassium) carboxylates reacted with α-chloroacetates at room temperature or reacted with alkyl bromides (chlorides) at 60℃ to give the corresponding (α-alkoxyformacyl)methyl carboxylic esters and carboxylic esters in >90% yields. The catalytic mechanism was discussed.

Key words: cesium chloride, sodium (potassium) carboxylates, alkyl bromides (chlorides), esterification

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Liu Wenqi, Qi Jianyong, Chen Jinyang, Li Ningbo, Qui Renhua, Xu Xinhua. Cesium Chloride Catalysized the Reaction of Sodium (Potassium) Carboxylates with Alkyl Bromides (Chlorides)[J]. Chin. J. Org. Chem., 2013, 33(01): 190-194.

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氯化铯催化羧酸钠(钾)与α-氯代乙酸酯及溴(氯)代烃反应

Cesium Chloride Catalysized the Reaction of Sodium (Potassium) Carboxylates with Alkyl Bromides (Chlorides)

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