Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp3-C—H Bonds

doi:10.6023/cjoc201305052

Chin. J. Org. Chem. ›› 2013, Vol. 33 ›› Issue (11): 2430-2434.DOI: 10.6023/cjoc201305052 Previous Articles Next Articles

Notes

四丁基碘化铵催化的sp³-C—H键的磷酸酯化

王倩, 徐洲

徐州医学院基础学院生化与化学综合实验室徐州 221004

收稿日期:2013-05-30 修回日期:2013-07-08 发布日期:2013-07-11
通讯作者: 王倩 E-mail:qianwangchem@163.com
基金资助:
江苏省高校自然科学基金（No. 10KJB150018）资助项目.

Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp³-C—H Bonds

Wang Qian, Xu Zhou

Experimental Center for Biochemistry and Chemistry Teaching, School of Basic Sciences, Xuzhou Medical College, Xuzhou 221004

Received:2013-05-30 Revised:2013-07-08 Published:2013-07-11
Supported by:
Project supported by the Natural Science Foundation of Higher Education Institutions of Jiangsu Province (No. 10KJB150018).

Activation of sp³-C—H bonds and oxidative phosphonation of sp³-C—H bonds adjacent to a nitrogen atom of tertiary amine were catalyzed by tetrabutylammonium iodide (TBAI) with t-butylhydroperoxide (TBHP) as oxidant under mild reaction conditions. The safe, convenient, and environmentally benign process, as well as the broad substrate scope, low catalyst loading, high selectivity, short reaction time, and good yields make the protocol very practical.

Key words: sp³-C—H activation, oxidative coupling, phosphate, TBAI

Cite this article

Wang Qian, Xu Zhou. Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp³-C—H Bonds[J]. Chin. J. Org. Chem., 2013, 33(11): 2430-2434.

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四丁基碘化铵催化的sp³-C—H键的磷酸酯化

Tetrabutylammonium Iodide-Catalyzed Phosphonation of sp³-C—H Bonds

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四丁基碘化铵催化的sp3-C—H键的磷酸酯化