Research on Particle Size of Organic Semiconductor Materials Poly(3-hexylthiophene) and [6,6]-Phenyl-C60-butyric Acid Methyl Ester in Chlorobenzene Solution

doi:10.6023/cjoc201405029

Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (11): 2370-2375.DOI: 10.6023/cjoc201405029 Previous Articles Next Articles

Notes

有机半导体材料聚(3-己基噻吩)及[6,6]-苯基-C60丁酸甲酯在氯苯溶液中粒径研究

李晨希^a, 董兵超^b, 李萌^a, 王金淼^a, 蔡雯君^a, 牛贺莹^a, 马恒^a

a 河南师范大学物理与电子工程学院新乡 453007;
b 新乡医学院应用物理研究室新乡 453003

收稿日期:2014-05-20 修回日期:2014-06-23 发布日期:2014-07-03
通讯作者: 马恒,hengma@henannu.edu.cn E-mail:hengma@henannu.edu.cn
基金资助:
国家自然科学基金(No.11074066)资助项目.

Research on Particle Size of Organic Semiconductor Materials Poly(3-hexylthiophene) and [6,6]-Phenyl-C60-butyric Acid Methyl Ester in Chlorobenzene Solution

Li Chenxi^a, Dong Bingchao^b, Li Meng^a, Wang Jingmiao^a, Cai Wenjun^a, Niu Heying^a, Ma Heng^a

a College of Physics and Electronic Engineering, Henan Normal University, Xinxiang 453007;
b Institute of Applied Physics, Xinxiang Medical University, Xinxiang 453007

Received:2014-05-20 Revised:2014-06-23 Published:2014-07-03
Supported by:
Project supported by the National Natural Science Foundation of China (No.11074066).

The mixture of organic semiconductor electron donor poly(3-hexylthiophene) (P3HT) and acceptor [6,6]-phenyl- C60-butyric acid methyl ester (PCBM) is dissolved in chlorobenzene for measuring the solute particle diameter. By comparing the performance of solar cells and the surface morphology of the active layer, the dispersion law of the mixed solutes in chlorobenzene is analyzed. The influence of temperature and concentration on particle size, furthermore, the impact of particle size on device performance are discussed. The results show that most of the particle sizes in the solution are populated at about 4000 nm, and both the concentration and the temperature of the solution have a significant effect on the particle size of the solution. For low concentration solution, the particle sizes are greatly influenced by temperature. On the contrary, the effect of temperature on the particle size in the solution concentration is less apparent when the concentration becomes higher. When the solution concentration reaches 12.67 mg/mL, it has a preferably dispersion and optimal fill factor. When the concentration reaches 19.00 mg/mL, the solar cell made by the solution shows a well property on power conversion efficiency and short-circuits current.

Key words: polymer, chlorobenzene, particle size, organic solar cells, P3HT:PCBM

Cite this article

Li Chenxi, Dong Bingchao, Li Meng, Wang Jingmiao, Cai Wenjun, Niu Heying, Ma Heng. Research on Particle Size of Organic Semiconductor Materials Poly(3-hexylthiophene) and [6,6]-Phenyl-C60-butyric Acid Methyl Ester in Chlorobenzene Solution[J]. Chin. J. Org. Chem., 2014, 34(11): 2370-2375.

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有机半导体材料聚(3-己基噻吩)及[6,6]-苯基-C60丁酸甲酯在氯苯溶液中粒径研究

Research on Particle Size of Organic Semiconductor Materials Poly(3-hexylthiophene) and [6,6]-Phenyl-C60-butyric Acid Methyl Ester in Chlorobenzene Solution

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