Chinese Journal of Organic Chemistry ›› 2023, Vol. 43 ›› Issue (8): 2699-2710.DOI: 10.6023/cjoc202212026 Previous Articles     Next Articles

Special Issue: 二氧化碳虚拟合辑


廖旭a,b, 王泽宇b, 唐武飞a,*(), 林金清b,*()   

  1. a 湖南科技学院化学与生物工程学院 湖南永州 425199
    b 华侨大学材料科学与工程学院 福建厦门 361021
  • 收稿日期:2022-12-20 修回日期:2023-03-28 发布日期:2023-04-21
  • 基金资助:
    国家自然科学基金(21246008); 国家自然科学基金(21803021); 福建省自然科学基金(2020J01065); 湖南省自然科学基金(2023JJ40298)

Progress in Porous Organic Polymer for Chemical Fixation of Carnbon Dioxide

Xu Liaoa,b, Zeyu Wangb, Wufei Tanga(), Jinqing Linb()   

  1. a College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou, Hunan 425199
    b College of Materials Science and Engineering, Huaqiao University, Xiamen, Fujian 361021
  • Received:2022-12-20 Revised:2023-03-28 Published:2023-04-21
  • Contact: *E-mail:;
  • Supported by:
    The National Natural Science Foundation of China(21246008); The National Natural Science Foundation of China(21803021); The Natural Science Foundation of Fujian Province(2020J01065); The Hunan Provincial Natural Science Foundation(2023JJ40298)

Porous organic polymers (POPs) are a new class of porous materials that connect organic structural units by covalent bonds, having the features of various synthetic methods, adjustable pore properties, stable pore structures, low relative density and large specific surface areas. POPs have been applied in fields of gas adsorptions, separations and storage, optoelectronic devices, sensing and heterogeneous catalysis, showing the important application value. Carbon capture, utilization and storage (CCUS) technology is the unique way to significantly reduce carbon dioxide (CO2) emissions from fossil fuels, and catalytic conversion of CO2 into valuable fuels or industrial value-added products is an effective and potential strategy to solve the utilization of renewable energy and realize the development of green chemistry. In this review, the synthesis and properties of covalent-organic frameworks (COFs), covalent triazine frameworks (CTFs), hypercrosslinked polymers (HCPs), conjugated microporous polymers (CMPs) and polymer of intrinsic microporosity (PIMs) and their progress of chemical fixation of CO2 in recent years, is reviewed, and the application prospects of POPs in CO2 catalysis are prospected.

Key words: porous organic polymers, heterogeneous catalysis, chemical fixation, carbon dioxide conversion, industrial value-added products