PhI(OAc)2/I2-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters

doi:10.6023/cjoc201506024

Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (12): 2552-2558.DOI: 10.6023/cjoc201506024 Previous Articles Next Articles

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PhI(OAc)₂/I₂介导下氮烷氧基酰胺的氧化自身偶联成酯的方法

段希焱^a, 段希斌^b, 杨坤^a, 王志成^a, 张璐^a, 佟悦^a, 刘浩哲^a, 杜珂^a, 唐榕泽^a

a 河南科技大学化工与制药学院洛阳 471023;
b 郑州大学附属郑州中心医院郑州 450007

收稿日期:2015-06-18 修回日期:2015-07-24 发布日期:2015-08-26
通讯作者: 段希焱 E-mail:duanxiyan@tju.edu.cn
基金资助:
河南科技大学博士科研启动项目(No. 4008-13480042).

PhI(OAc)₂/I₂-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters

Duan Xiyan^a, Duan Xibin^b, Yang Kun^a, Wang Zhicheng^a, Zhang Lua^a, Tong Yue^a, Liu Haozhe^a, Du Ke^a, Tang Rongze^a

a School of Chemical Engineering & Pharmaceutics, Henan University of Science and Technology, Luoyang 471023;
b Zhengzhou Certral Hospital Affiliated to Zhengzhou University, Zhengzhou 450007

Received:2015-06-18 Revised:2015-07-24 Published:2015-08-26
Supported by:
Project supported by the Students Research Training Program of Henan University of Science and Technology (No. 4008-13480042).

1. PhI(OAc)₂/I₂-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters.PDF(1767KB)

Abstract

A variety of substituted N-alkoxyamides derivatives were found to be converted to the corresponding esters mediated by PhI(OAc)₂/I₂. This novel strategy allows for an efficient synthesis of esters and is highlighted by appealing features such as readily available of the starting material, mild reaction condition, wide substrate scope and transition-metal-free characteristics.

Key words: hypervalent iodine, N-alkoxyamides, ester, oxidative coupling

Cite this article

Duan Xiyan, Duan Xibin, Yang Kun, Wang Zhicheng, Zhang Lua, Tong Yue, Liu Haozhe, Du Ke, Tang Rongze. PhI(OAc)₂/I₂-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters[J]. Chin. J. Org. Chem., 2015, 35(12): 2552-2558.

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PhI(OAc)₂/I₂介导下氮烷氧基酰胺的氧化自身偶联成酯的方法

PhI(OAc)₂/I₂-Mediated Oxidative Homocoupling of N-Alkoxyamides: An Approach to Esters

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PhI(OAc)2/I2介导下氮烷氧基酰胺的氧化自身偶联成酯的方法