Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light

doi:10.6023/cjoc201603002

Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (9): 2121-2129.DOI: 10.6023/cjoc201603002 Previous Articles Next Articles

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可见光下曙红Y催化的吲哚酮类化合物的合成

田文艳^a,b, 徐松^a,b,c, 梁中卫^a,b, 孙德立^a,b, 张荣华^a,b

a 同济大学化学系上海 200092;
b 上海市化学评估与可持续发展重点实验室上海 200092;
c 嘉兴学院化学与制药工程学院嘉兴 31400

收稿日期:2016-03-03 修回日期:2016-04-29 发布日期:2016-05-19
通讯作者: 张荣华 E-mail:rhzhang@tongji.edu.cn
基金资助:
国家自然科学基金（No.20972113/B020502）资助项目.

Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light

Tian Wenyan^a,b, Xu Song^a,b,c, Liang Zhongwei^a,b, Sun Deli^a,b, Zhang Ronghua^a,b

a Department of Chemistry, Tongji University, Shanghai 200092;
b Shanghai Key Laboratory of Chemical Assessment and Sustainability, Shanghai 200092;
c College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 31400

Received:2016-03-03 Revised:2016-04-29 Published:2016-05-19
Supported by:
Project supported by the National Natural Science Foundation of China (No.20972113/B020502).

1. Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light.PDF(734KB)

Abstract

A novel visible-light-introduced reaction for the construction of oxindole derivatives via tandem radical cyclization of N-aryl acrylamides with diethyl bromomalonate has been developed. The reaction has been achieved in high yield under mild conditions by using Eosin Y as photocatalyst, which is cheap, easy to handle and environmentally friendly. It might provide a promising protocol for the synthesis of oxindole derivatives.

Key words: eosin Y, photoredox catalysis, oxindoles, radical cyclization

Cite this article

Tian Wenyan, Xu Song, Liang Zhongwei, Sun Deli, Zhang Ronghua. Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light[J]. Chin. J. Org. Chem., 2016, 36(9): 2121-2129.

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可见光下曙红Y催化的吲哚酮类化合物的合成

Synthesis of Oxindoles by Eosin Y Catalyzed under Visible Light

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