Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl2(Py) and Its Efficient Application in Coupling Reaction

doi:10.6023/cjoc201705027

Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (11): 2948-2955.DOI: 10.6023/cjoc201705027 Previous Articles Next Articles

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一种含吡啶配体氮杂环卡宾钯络合物(NHC)PdCl₂(Py)的合成及其高效催化偶联反应

袁航^a, 陈惠莲^a, 罗治斌^b, 高玉华^a, 陆鸿飞^a

a 江苏科技大学环境与化学工程学院镇江 212003;
b 江苏大学化工学院镇江 212003

收稿日期:2017-05-17 修回日期:2017-07-13 发布日期:2017-08-11
通讯作者: 陆鸿飞 E-mail:zjluhf1979@hotmail.com
基金资助:
国家自然科学基金（No.21402067）资助项目.

Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl₂(Py) and Its Efficient Application in Coupling Reaction

Yuan Hang^a, Chen Huilian^a, Luo Zhibin^b, Gao Yuhua^a, Lu Hongfei^a

a School of Envionmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003;
b School of Chemical Engineering, Jiangsu University, Zhenjiang 212003

Received:2017-05-17 Revised:2017-07-13 Published:2017-08-11
Contact: 10.6023/cjoc201705027 E-mail:zjluhf1979@hotmail.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21402067).

1. Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl₂(Py) and Its Efficient Application in Coupling Reaction.PDF(3407KB)

Abstract

A Pd-pyridine N-heterocyclic carbene complex (NHC)PdCl₂(Py) has been synthesized through two steps and successfully applied as an effective catalyst for the Suzuki coupling reaction, Heck coupling reaction and Sonogashira coupling reaction. The catalyst demonstrates excellent catalytic activity in Suzuki coupling reaction and Sonogashira coupling reaction with a catalyst loading of 0.1 mol% and 1 mol% in Heck coupling reaction.

Key words: carbene, suzuki coupling, Heck coupling, Sonogashira coupling

Cite this article

Yuan Hang, Chen Huilian, Luo Zhibin, Gao Yuhua, Lu Hongfei. Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl₂(Py) and Its Efficient Application in Coupling Reaction[J]. Chin. J. Org. Chem., 2017, 37(11): 2948-2955.

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一种含吡啶配体氮杂环卡宾钯络合物(NHC)PdCl₂(Py)的合成及其高效催化偶联反应

Synthesis of a Pd-Pyridine N-Heterocyclic Carbene Complex (NHC)-PdCl₂(Py) and Its Efficient Application in Coupling Reaction

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一种含吡啶配体氮杂环卡宾钯络合物(NHC)PdCl2(Py)的合成及其高效催化偶联反应