Cu2O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases

doi:10.6023/cjoc201712038

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (6): 1556-1561.DOI: 10.6023/cjoc201712038 Previous Articles Next Articles

Special Issue: 碳氢活化合辑2018-2019

Notes

无碱条件下的Cu₂O催化绿色氧化端基炔偶联

马楠, 曾祥华

嘉兴学院生物与化学工程学院嘉兴 314001

收稿日期:2017-12-27 修回日期:2018-01-31 发布日期:2018-02-11
通讯作者: 曾祥华,E-mail:xianghuazeng@mail.zjxu.edu.cn E-mail:xianghuazeng@mail.zjxu.edu.cn
基金资助:
浙江省自然科学基金（No.LY17B030011）及嘉兴市科技计划（No.2015AY11014）资助项目.

Cu₂O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases

Ma Nan, Zeng Xianghua

College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing 314001

Received:2017-12-27 Revised:2018-01-31 Published:2018-02-11
Contact: 10.6023/cjoc201712038 E-mail:xianghuazeng@mail.zjxu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of Zhejiang Province (No. LY17B030011) and the Jiaxing Science and Technology Project (No. 2015AY11014).

1. Cu₂O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases.PDF(1107KB)

Abstract

A high efficient method for the synthesis of 1,3-diynes derivatives which employed terminal alkynes as the substrates and copper(I) oxide as the catalyst was developed. This method possessed the character of base-free and mild reaction conditions. The reaction mechanism was also studied. Furthermore, this reaction could be magnified to gram scale and the catalyst of copper(I) oxide could be recycled.

Key words: copper (I) oxide, homocoupling, terminal alkynes, base-free

Cite this article

Ma Nan, Zeng Xianghua. Cu₂O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases[J]. Chin. J. Org. Chem., 2018, 38(6): 1556-1561.

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无碱条件下的Cu₂O催化绿色氧化端基炔偶联

Cu₂O-Catalyzed Green Oxidative Terminal Alkynes Homocoupling without Bases

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无碱条件下的Cu2O催化绿色氧化端基炔偶联