Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes

doi:10.6023/cjoc201805007

Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (12): 3219-3226.DOI: 10.6023/cjoc201805007 Previous Articles Next Articles

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含氮刚性杂环取代香豆素类染料敏化剂的合成及光电性能

蒋绍亮^a, 刘杰^b, 崔艳红^b, 吴华彪^b, 韩亮^b

a 浙江工业大学药学院杭州 310017;
b 浙江工业大学化工学院杭州 310017

收稿日期:2018-05-02 修回日期:2018-07-20 发布日期:2018-08-23
通讯作者: 韩亮 E-mail:hanliang814@163.com
基金资助:
国家自然科学基金（No.21406202）资助项目.

Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes

Jiang Shaoliang^a, Liu Jie^b, Cui Yanhong^b, Wu Huabiao^b, Han Liang^b

a College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310017;
b College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310017

Received:2018-05-02 Revised:2018-07-20 Published:2018-08-23
Contact: 10.6023/cjoc201805007 E-mail:hanliang814@163.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21406202).

1. Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes.PDF(464KB)

Abstract

Two novel nitrogen-containing rigid heterocycle substituted coumarin sensitizing dyes were designed and synthesized with nitrogen-containing rigid heterocycle substituted coumarin as the electron donor, biphenyl or phenylthiophene as π bridge and cyanoacrylic acid as the electron acceptor. Their spectral properties, charge recombination rate and photovoltaic performance were compared with those of the corresponding diethylaminocoumarin sensitizing dyes. The results show that the incorporation of nitrogen-containing rigid heterocycle leads to the broadening of the absorption spectrum and the improvement of light-harvesting ability. In the dye with phenylthiophene as π bridge, the presence of nitrogen-containing rigid heterocycle distinctly weakens the molecular planarity, decreases the charge recombination rate and improves V_OC. Therefore, among four coumarin sensitizing dyes, nitrogen-containing rigid heterocycle coumarin sensitizing dye with phenylthiophene π bridge exhibits the optimal photoelectric conversion efficiency 3.89% due to its better J_SC, highest V_OC and fill factor (ff).

Key words: coumarin, dye sensitizer, nitrogen-containing rigid heterocylce, synthesis, photoelectric conversion efficiency

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Jiang Shaoliang, Liu Jie, Cui Yanhong, Wu Huabiao, Han Liang. Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes[J]. Chin. J. Org. Chem., 2018, 38(12): 3219-3226.

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含氮刚性杂环取代香豆素类染料敏化剂的合成及光电性能

Syntheses and Photovoltaic Performance of Nitrogen-Containing Rigid Heterocycle Substituted Coumarin Sensitizing Dyes

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