Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I3-/I2 Adsorption Property

doi:10.6023/cjoc201807054

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (1): 151-156.DOI: 10.6023/cjoc201807054 Previous Articles Next Articles

Special Issue: 庆祝陈庆云院士九十华诞；有机超分子化学合辑

Articles

环糊精/氨基粘土超分子水凝胶的构筑及其I₃^-/I₂吸附性能

牛杰^a, 陈湧^a, 刘育^a,b

a 南开大学化学学院元素有机化学国家重点实验室天津 300071;
b 天津市化学化工协同创新中心天津 300072

收稿日期:2018-07-29 修回日期:2018-09-17 发布日期:2018-09-26
通讯作者: 刘育 E-mail:yuliu@nankai.edu.cn
基金资助:
国家自然科学基金（Nos.21432004，21672113，21772099，21861132001，91527301）资助项目.

Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property

Niu Jie^a, Chen Yong^a, Liu Yu^a,b

a State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071;
b Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072

Received:2018-07-29 Revised:2018-09-17 Published:2018-09-26
Contact: 10.6023/cjoc201807054 E-mail:yuliu@nankai.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21432004, 21672113, 21772099, 21861132001, 91527301).

1. Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property.PDF(3057KB)

Abstract

Aminoclay (AC), as a kind of layered silicates with positive charges, shows high dispersity in water and has been widely applied in the fabrication of intelligent hybrid hydrogel. Herein, heptakis-[6-deoxy-6-(2-sulfanylethanesulfonic acid)]-β-cyclodextrin (SCD), a kind of negatively charged cyclodextrin, was employed to construct the supramolecular hydrogel with aminoclay through the static electronic interactions, and the resultant SCD-AC hydrogel was fully characterized by means of X-ray powder diffraction (XRD), scanning electronic microscopy (SEM), fourier transform infrared spectroscopy (FT-IR), zeta potential, rheological test, etc. Significantly, the SCD-AC hydrogel can efficiently absorb not only I₃^- ion in aqueous solution but also I₂ molecule in organic solvent, giving a high adsorption capacity up to 90% with 10 min.

Key words: supramolecular hydrogel, cyclodextrin, aminoclay, iodine, adsorption

Cite this article

Niu Jie, Chen Yong, Liu Yu. Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property[J]. Chin. J. Org. Chem., 2019, 39(1): 151-156.

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环糊精/氨基粘土超分子水凝胶的构筑及其I₃^-/I₂吸附性能

Construction of Cyclodextrin/Aminoclay-Based Supramolecular Hydrogel and Its I₃^-/I₂ Adsorption Property

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环糊精/氨基粘土超分子水凝胶的构筑及其I3-/I2吸附性能