N,N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu2+ and Ni2+ Ion

doi:10.6023/cjoc201807042

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (2): 427-433.DOI: 10.6023/cjoc201807042 Previous Articles Next Articles

Special Issue: 荧光探针-生物传感合辑

ARTICLE

N,N-二(2-吡啶甲基)胺基三聚茚衍生物的合成及对铜离子、镍离子的选择性识别

朱阳明^a, 王忠龙^a, 杨剑^a, 徐徐^a, 王石发^a, 蔡正春^a, 徐海军^a,b

a 南京林业大学化学工程学院江苏生物质能源与化学品重点实验室南京 210037;
b 江苏省生物质能源与材料重点实验室南京 210042

收稿日期:2018-07-23 修回日期:2018-09-25 发布日期:2018-10-12
通讯作者: 徐海军 E-mail:xuhaijun@njfu.edu.cn
基金资助:
江苏省自然科学基金（No.BK20151513）、霍英东教育基金（No.141030）、江苏省生物质能源与材料重点实验室（No.JSBGFC12002）及江苏高校优势学科建设工程（PAPD）资助项目.

N,N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion

Zhu Yangmin^a, Wang Zhonglong^a, Yang Jian^a, Xu Xu^a, Wang Shifa^a, Cai Zhengchun^a, Xu Haijun^a,b

a College of Chemical Engineering, Jiangsu Key Laboratory of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037;
b Jiangsu Key Laboratory for Biomass Energy and Material of Jiangsu Province, Nanjing 210042

Received:2018-07-23 Revised:2018-09-25 Published:2018-10-12
Contact: 10.6023/cjoc201807042 E-mail:xuhaijun@njfu.edu.cn
Supported by:
Project supported by the Natural Science Foundation of Jiangsu Province (No. BK20151513), the Fok Ying Tung Education Foundation (No. 141030), the Fund from Jiangsu Key Laboratory for Biomass Energy and Material (No. JSBEM201702) and the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

1. N,N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion.PDF(895KB)

Abstract

A new turn-off probe 6 was synthesized from bis(pyridin-2-ylmethyl)amine and truxene derivatives, and its structure was confirmed by ¹H NMR and HRMS. The recognition behaviors of 6 to various metal ions were investigated and the results show that 6 exhibited good selectivity and high sensitivity to Cu²⁺ and Ni²⁺ with good anti-interference. The probe 6 presented apparent fluorescence quenching in DMF/H₂O (V/V=8/2, pH=7.0) solution toward Cu²⁺ and Ni²⁺. HRMS analysis showed a 1:1 binding stoichiometry between 6 and Cu²⁺ or Ni²⁺. The detection limit for Cu²⁺ and Ni²⁺ was calculated to be 28 and 41 nmol/L, respectively. The detection limit of 6 for Cu²⁺ and Ni²⁺ was far lower than the maximum allowable level of World Health Organization (WHO) limit for drinking water.

Key words: truxene, bis(pyridin-2-ylmethyl)-amine (DPA), fluorescent sensor, Cu²⁺, Ni²⁺

Cite this article

Zhu Yangmin, Wang Zhonglong, Yang Jian, Xu Xu, Wang Shifa, Cai Zhengchun, Xu Haijun. N,N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion[J]. Chin. J. Org. Chem., 2019, 39(2): 427-433.

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N,N-二(2-吡啶甲基)胺基三聚茚衍生物的合成及对铜离子、镍离子的选择性识别

N,N-Bis(2-pyridylmethyl)amine-Based Truxene Derivative as a Highly Sensitive Fluorescence Sensor for Cu²⁺ and Ni²⁺ Ion

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