Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (6): 1745-1751.DOI: 10.6023/cjoc201912007 Previous Articles     Next Articles


马学林a,b, 韩利民a, 张骁勇b, 张玉恒b, 王丽b, 杨坤b, 冀婕b   

  1. a 内蒙古工业大学化工学院 呼和浩特 010051;
    b 包头师范学院化学学院 内蒙古包头 014030
  • 收稿日期:2019-12-06 修回日期:2020-02-27 发布日期:2020-03-31
  • 通讯作者: 韩利民, 张骁勇;
  • 基金资助:

Triazine Derivative for Fluorescence Sensing of Zr4+, Fe3+ Ions and Acetone

Ma Xuelina,b, Han Limina, Zhang Xiaoyongb, Zhang Yuhengb, Wang Lib, Yang Kunb, Ji Jieb   

  1. a Chemical Engineering College, Inner Mongolia University of Technology, Hohhot 010051;
    b Department of Chemistry, Baotou Teachers'College, Baotou, Inner Mongolia 014030
  • Received:2019-12-06 Revised:2020-02-27 Published:2020-03-31
  • Supported by:
    Project supported by the Natural Science Foundation of Inner Mongolia (Nos. 2018BS02009, 2019MS02031), the Young Innovative Talents in Baotou City (No. 30324001), the National Natural Science Foundation of China (Nos. 21767021, 51563019) and the Education Department Project of Inner Mongolia (No. NJZY19187).

2,2',2''-(1,3,5-Triazine-2,4,6-triimino)tribenzoic acid (L, H3TATIB) fluorescence response chemosensor has been synthesized by one pot reaction and its fluorescent behaviors to transition metal ions were systematically investigated. The experimental results show that the recognition of Zr4+ and Fe3+ is realized in N,N-dimethylformamide (DMF) aqueous solution; The compound L can effectively detect acetone in organic solvent. The detection limits of Zr4+ and Fe3+ are 3.60×10-6 and 1.33×10-6 mol/L, respectively. It was preliminarily explored that compound L was used as a fluorescent probe to identify Fe3+ ion in human urine and water samples.

Key words: fluorescent sensor, Zr4+ ion, Fe3+ ion, acetone, 1,3,5-triazine derivatives