Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves

doi:10.6023/cjoc201808032

Chin. J. Org. Chem. ›› 2019, Vol. 39 ›› Issue (4): 1181-1186.DOI: 10.6023/cjoc201808032 Previous Articles Next Articles

Special Issue: 有机硅化学虚拟合辑

Notes

苯胺基于钛硅分子筛的选择性氧化合成氧化偶氮苯

宋玉婉, 冯韶静, 韩维, 肖亚平

南京师范大学化学与材料科学学院南京 210023

收稿日期:2018-08-28 修回日期:2018-11-13 发布日期:2018-11-30
通讯作者: 韩维, 肖亚平 E-mail:hanwei@njnu.edu.cn;xiaoyaping@njnu.edu.cn
基金资助:
国家自然科学基金（Nos.21776139，21302099）、江苏省自然科学基金（No.BK20161553）、江苏省高效自然科学基金（No.16KJB150019）资助项目.

Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves

Song Yuwan, Feng Shaojing, Han Wei, Xiao Yaping

School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023

Received:2018-08-28 Revised:2018-11-13 Published:2018-11-30
Contact: 10.6023/cjoc201808032 E-mail:hanwei@njnu.edu.cn;xiaoyaping@njnu.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos.21776139,21302099),the Natural Science Foundation of Jiangsu Province (No.BK20161553),the Natural Science Foundation of Jiangsu Provincial Colleges and Universities (No.16KJB150019).

1. Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves.PDF(2259KB)

Abstract

A convenient method for improving the conversion and selectivity of aniline to azoxybenzene by adjusting the ratio of silicon to titanium of TS-1 is reported. Over TS-1 (80), aryl anilines are transformed into the corresponding azoxybenzenes in good yields with H₂O₂ as the oxidant. The effect of different reaction parameters like molar ratio of H₂O₂ to aniline, solvent and the activity in catalyst recycling has been studied.

Key words: anilines, oxidation, azoxybenzene, H₂O₂

Cite this article

Song Yuwan, Feng Shaojing, Han Wei, Xiao Yaping. Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves[J]. Chin. J. Org. Chem., 2019, 39(4): 1181-1186.

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苯胺基于钛硅分子筛的选择性氧化合成氧化偶氮苯

Synthesis of Azoxybenzenes by Selective Oxidation of Anilines on Titanium Silicate Molecular Sieves

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