Supramolecular Copolymers Driven by Quadruple Hydrogen Bonding and Host-Guest Interactions

doi:10.6023/cjoc201911014

Abstract

A heteroditopic monomer (H) comprised of ureidopyrimidinone (UPy) group and benzo-21-crown-7 motif and a homoditopic monomer (G) containing two dialkylammonium salt units have been successfully prepared. The functional groups both in H and G are linked together by a short spacer. Through quadruple hydrogen bonds, H can self-assemble into dimers, which are capable of complexing with G via host-guest interaction to form linear supramolecular copolymers. The supramolecular copolymers were fully characterized by various techniques, such as concentration-dependent ¹H NMR, viscosity measurements, and scanning electron microscope (SEM). The results will inspire the orthogonal construction of supramolecular polymers for smart materials in more fields.

Key words: supramolecular chemistry, quadruple hydrogen bonds, self-assembly, supramolecular polymer, crown ethers, macrocycles, host-guest interaction

Cite this article

Xiao Tangxin, Zhou Ling, Wei Xiaoyan, Li Zhengyi, Sun Xiaoqiang. Supramolecular Copolymers Driven by Quadruple Hydrogen Bonding and Host-Guest Interactions[J]. Chinese Journal of Organic Chemistry, 2020, 40(4): 944-949.

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利用四重氢键和主客体作用构筑超分子共聚物