Recent Process in the in situ Generated Metal Nanocluster Catalysis

doi:10.6023/cjoc202203060

Abstract

In transition metal catalyzed reactions using simple metal salts, metal complexes, or nanoparticles as catalyst precursors, the metal sources may transfer to other species in situ, such as mono metal species, metal clusters and nanoparticles. Herein, the representative examples of the in situ generated metal nanoclusters as the catalytically active species in synthetic methodologies are reviewed, including their in situ formation, characterization and effect in catalysis.

Key words: in situ generation, metal nanoclusters, catalytic methodology, transition-metal catalysis

Cite this article

Jinyu Zhang, Tianfen Liu, Le Wang, Xiaoming Wang. Recent Process in the in situ Generated Metal Nanocluster Catalysis[J]. Chinese Journal of Organic Chemistry, 2022, 42(8): 2331-2341.

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Fig. & Tab. 19

Figure 1. Possible metal species in homogeneous catalysis

Figure 2. [RhCp*Cl2]2 catalyzed hydrogenation of benzene

Figure 3. Rhodium clusters catalyzed the hydrogenation of N-heteroaromatic hydrocarbons

Figure 4. CAAC-Rh catalyzed hydrogenation of aromatic rings

Figure 5. Formation of rhodium nanoparticles in the catalytic hydrogenation of aromatic rings

Figure 6. Iron catalyzed hydrogenation of alkenes and alkynes

Figure 7. Soluble iron clusters catalyzed hydrogenation of olefins

Figure 8. Cobalt-catalyzed controllable hydrogenation of nitriles

Figure 9. Cobalt nanoparticles catalyzed hydrogenation of C=C, C=O and C=N bonds

Figure 10. Chromium‐catalyzed semi‐hydrogenation of alkynes

Figure 11. An easily accessed nickel nanoparticle catalyst for alkene hydrosilylation with tertiary silanes

Figure 12. Anti-Markovnikov selective hydrosilylation of alkynes catalyzed by platinum clusters

Figure 13. Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst

Figure 14. Selective benzylic C—H borylations by cobalt catalysis

Figure 15. Gold-catalyzed ester-assisted intermolecular hydration of alkynes and bromination of electron-rich arenes

Figure 16. In situ formed palladium clusters catalyzed coupling reaction

Figure 17. Copper clusters catalyzed Goldberg coupling reactions

Figure 18. Combined photoredox and iron catalysis for the cyclotrimerization of alkynes

Figure 19. Heterotopic Co catalyst for highly selective cyclotrimerization of alkynes

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