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Chinese Journal of Organic Chemistry >

2022 , Vol. 42 >Issue 2: 323 - 343

DOI: https://doi.org/10.6023/cjoc202109017

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Recent Progress in Direct Catalytic C(sp3)—H Silylation Reactions

  • Yi Cheng ,
  • Rongjing Hu ,
  • Xiaoqi Chen ,
  • Hao Yang ,
  • Xiaokang Niu ,
  • Lei Yang
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  • Key Laboratory of Organosilicon Chemistry and Material Technology, Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121
* Corresponding authors. E-mail: ;

Received date: 2021-09-13

  Revised date: 2021-10-06

  Online published: 2022-02-24

Supported by

Xihu Scholar Program and the Start-Up Grant from Hangzhou Normal University(2019DL018)

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Abstract

Organosilicon compounds containing C(sp3)—Si bonds are widely used in many research fields, such as material science, pharmaceutical chemistry and fine chemical synthesis. In recent years, due to its high atomic economy and step economy properties, the direct catalytic silylation of C(sp3)—H bonds to form C(sp3)—Si bonds has become one of the research hotspots in the syntheis of new organosilicones containing C(sp3)—Si bonds. The research progress of direct catalytic silylation of C(sp3)—H bonds is summarized in detail, and the mechanism and application range of related silylation reactions are also discussed.

Key words： transition-metal; C(sp3)—H silylation; C(sp3)—Si bond; organosilicone; non-transition metal

Cite this article

Yi Cheng , Rongjing Hu , Xiaoqi Chen , Hao Yang , Xiaokang Niu , Lei Yang . Recent Progress in Direct Catalytic C(sp3)—H Silylation Reactions[J]. Chinese Journal of Organic Chemistry, 2022 , 42(2) : 323 -343 . DOI: 10.6023/cjoc202109017

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