Chinese Journal of Organic Chemistry >
Synthesis of β-Oxopropylcarbamates Catalyzed by ZnO/Ionic Liquids under Atmospheric CO2
Received date: 2022-01-11
Revised date: 2022-04-02
Online published: 2022-04-29
Supported by
National Natural Science Foundation of China(22102127); National Natural Science Foundation of China(21950410754); State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences(GZKF202023); Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education ;Hubei Key Laboratory of Catalysis and Materials Science(CHCL19002)
Carbamate compounds exhibit a broad applicable scope in medicine, pesticide, resin modification, fabric finishing and organic synthesis. A methodology using ZnO/ionic liquids as the catalyst for the three-component coupling reactions of carbon dioxide (CO2), secondary amines and propargylic alcohols to produce various β-oxopropylcarbamates was developed. This catalytic system exhibited robust recyclability and broad substrate scope. Moreover, it showed considerable catalytic activity under atmospheric CO2, indicating its potential in carbon capture and utilization processes.
Yong Xu , Yongxing Zhang , Jia Hu , Cheng Chen , Ye Yuan , Francis Verpoort . Synthesis of β-Oxopropylcarbamates Catalyzed by ZnO/Ionic Liquids under Atmospheric CO2[J]. Chinese Journal of Organic Chemistry, 2022 , 42(8) : 2542 -2550 . DOI: 10.6023/cjoc202201015
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