Chinese Journal of Organic Chemistry >
Design and Synthesis of Novel Aggregation-Induced Luminescence Molecules Based on Isoquinoline
Received date: 2022-04-15
Revised date: 2022-06-18
Online published: 2022-07-14
Supported by
National Natural Science Foundation of China(21877034); Natural Science Foundation of Hunan Provincial(2020JJ4028); Postgraduate Scientific Research Innovation Project of Hunan Province(2021RC5028); Science and Technology Foundation of Henan Province(212102210202)
Aggregation induced emission (AIE) molecules have been widely used in chemistry, biosensor, cell imaging and organic light-emitting diode (OLED) due to their excellent spectral properties. It was found for the first time that isoquinoline benzoxazine molecules exhibited good fluorescent emission in a high proportion of water/acetonitrile mixed solution, showing an obvious AIE phenomenon. On this basis, a novel type of AIE molecules fused with tetraphenylene and isoquinoline structural units were designed and synthesized. They were found exhibiting an excellent AIE phenomenon. It was confirmed by density functional theory (DFT) calculations that the splicing of the two structural units effectively reduced the energy gap of the frontier orbitals, which was helpful for the preparation of fluorescent molecules with longer emission wavelengths. In this study, AIE molecules based on the isoquinoline structure were discovered and prepared, which enriched the members of the AIE family. The AIE molecules based on the isoquinoline structure were first discovered and prepared in this study, which enriched the members of the AIE family.
Key words： isoquinoline; aggregation-induced emission; fluorescence; synthesis
Jiamin Tan , Yajun Yu , Meng Guan , Yunhui Zhao , Zilong Tang , Zhihua Zhou , Tao Guo . Design and Synthesis of Novel Aggregation-Induced Luminescence Molecules Based on Isoquinoline[J]. Chinese Journal of Organic Chemistry, 2022 , 42(11) : 3776 -3783 . DOI: 10.6023/cjoc202204038
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