化学学报 ›› 1983, Vol. 41 ›› Issue (1): 9-15. 上一篇    下一篇

研究论文

Py2MCl2络合物的生成热及其稳定性

刘金香;高秀英;尹安学   

  1. 中国科学院大连化学物理研究所
  • 发布日期:1983-01-15

Heats of formation and stabilities of complexes Py2MCl2.

LIU JINXIANG;GAO XIUYING;YIN ANXUE   

  • Published:1983-01-15

关键词: 稳定性, 吡啶 P, 金属络合物, 生成热

The stability of solid complexes can usually by characterized by the heat of formation of complexes from salts MXn and the ligand R in gaseous state. In order to evaluate the stability of a series of complexes Py2MCl2 (M=Cu, Ni, Co, Mn, Hg, Zn, Fe and Cd), the heats of formation of these complexes were measured by quantitative DTA experimentally and compared with that calculated by Yang Pin's method. Both results agree well. On the basis of these results stabilities of complexes Py2MCl2 were estimated.

Key words: STABILITY, PYRIDINE P, METAL COMPLEX, FORMATION HEAT

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