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化学学报
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化学学报 ›› 1989, Vol. 47 ›› Issue (3): 300-303. 上一篇    下一篇

研究论文

冠醚化合物的合成 X: 双酰胺双-(3'正十五烷基-苯并-15-冠-5)的合成

石正金;曾凡;黄载福   

  1. 武汉大学环科系
  • 发布日期:1989-03-15

The synthesis of crown ether compounds X: Synthesis of bis-3'-n-pentadecyl benzo-15-C-5 bisamides

SHI ZHENGJIN;ZENG FAN;HUANG ZAIFU   

  • Published:1989-03-15

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347

本文设计并合成了3'-正十五烷基-5'-硝基-苯并-15-冠-5(1)、3-正十五烷基-5'-氨基-苯并-15-冠-5(2)和十种双酰胺双(3'-正十五烷基-苯并-15-冠-5)(3a-3j), 其合成路线如下.

关键词: 酰胺, 红外分光光度法, 元素分析, 质谱法, 冠式化合物, 苯 P, 质子磁共振谱法, 十五碳化合物

The bis-3'-pentadecylbenzo-15-C-5 bisamides I (Z = phenylene, alkylene, CH2OCH2, etc.) were synthesized by the condensation of 5'-amino-3'-pentadecylbenzo-15-C-5 with diacyl chlorides in dry benzene. Their structures were confirmed by elemental anal., IR, 1H NMR, and mass spectrum data.

Key words: AMIDES, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, MASS SPECTROGRAPHY, CROWN ETHER COMPOUNDS, BENZENE P, PROTON MAGNETIC RESONANCE SPECTROMETRY, C15 COMPOUNDS

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