### 硫化对聚乙炔结构和性能的影响

1. 东北师范大学化学系
• 发布日期:1992-08-15

### The influence of sulfidation on the structure and properties of polyacetylene

FU YUJIE;SU ZHONGMIN;WANG RONGSHUN;XIE DEMIN

• Published:1992-08-15

The structure and properties of polyacetylene obtained by dehydrochlorination of PVC before and after sulfidation were studied by DSC and FTIR spectra. The mol. structure and electron properties of sulfided polyacetylene were calculated by CNDO/2 MO. Sulfidation greatly affected the energy level band structure, especially the energy band near HOCO and LUCO. The presence of S also changed the elec. charge distribution in the polymer.