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化学学报
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化学学报 ›› 1997, Vol. 55 ›› Issue (5): 508-514. 上一篇    下一篇

研究论文

三磺化酞菁在微乳液、胶束、醇-水体系中的二聚现象研究

吴星;袁诗海;姚荣;郭荣   

  1. 扬州大学师范学院化学化工系
  • 发布日期:1997-05-15

Study on the dimerization of trisulfophthalocyanine in the microemulsion micelles and monobasic alcohol system

WU XING;YUAN SHIHAI;YAO RONG;GUO RONG   

  • Published:1997-05-15

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435

被引次数

32 | 1

本文采用分光光度法研究了三磺化酞菁(S3Pc)在微乳液(Triton X-100-壬烷-正戊醇-水)、胶束(Triton X-100)、醇(甲、乙、丙醇)-水体系中的二聚现象。计算了S3Pc的二聚常数Kd。结果表明, S3Pc的Kd随着微乳液、胶束中表面活性剂的浓度的增加而减小; 随着醇-水溶液的羟基摩尔浓度(Mo-h)的增加而增加。

关键词: 分光光度法, 乙醇, 胶束, 二聚体, 甲醇, 丙醇, 微乳, 壬烷, 酞菁, 正戊醇

The dimerizaion of trisulfophthalocyanine (S3Pc) was studied in the microemulsion (Triton X-100-pentanol-nonane-water), micelles (Triton X-100) and aqueous alcoholic solution (MeOH, EtOH, PrOH) by spectrophotometry. The dimerization constants (Kd) of S3Pc were calculated. It was shown that Kd of S3Pc was decreased in the above mentioned system as compared with that in aqueous solution.

Key words: SPECTROPHOTOMETRY, ETHANOL, MICELLE, DIMER, METHANOL, PROPANOL, MICROEMUSION, NONANE, PHTHALOCYANIN (=PHTHALOCYANINE)

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