化学学报 ›› 2000, Vol. 58 ›› Issue (7): 731-736.    下一篇

研究论文

液晶聚合物的单层与Langmuir-Blodgett膜

陈晓;薛庆斌;杨孔章;张其震   

  1. 山东大学胶体与界面化学教育部重点实验室;山东大学化学系.济南(250100)
  • 发布日期:2000-07-15

Monolayers and langmuir-blodgett films of liquid crystalline polymers

Chen Xiao;Xue Qingbin;Yang Kongzhang;Zhang Qizhen   

  1. Shandong Univ, Dept Chem.Jian(250100)
  • Published:2000-07-15

系统研究了手性液晶聚硅氧烷和光致变色液晶聚硅氧烷两个毓的侧链液晶聚合物在空气/水界面的单层行为和Langmuir-Blodgett(LB)膜沉积特性,对LB膜结构与存在的聚集现象进行了系统的表征,并初步探讨了LB膜中液晶聚合物表现的功能性。

关键词: 液晶, L-B膜, 聚硅氧烷

Two series of the side-chain liquid crystalline polysiloxanes (LCPs), chiral LCPs and photochromic LCPs, were chosen to study their monolayer behaviors at the air/water interface when they were in pure states or mixed with arachidic acid (AA). Their LB film transfer properties and film structures were characterized as well. The aggregation phenomena in monolayers and LB multilayers were systematically characterized by different spectral and surface morphology observation methods. The functionality of these LCPs in LB films was preliminarily tested.

Key words: LIQUID CRYSTAL, L-B MEMBRANE, POLYSILOXANE

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