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化学学报
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化学学报 ›› 2005, Vol. 63 ›› Issue (18): 1699-1702. 上一篇    下一篇

研究论文

以表面活性剂为模板ZrO2薄膜在空气-水界面的自组装研究

刘孝恒*,1，WHITE, John2，汪信1   

  1. (1南京理工大学材料化学实验室 南京 210094)
    (2 澳大利亚国立大学化学研究所 堪培拉 0200 澳大利亚)
  • 投稿日期:2004-11-24 修回日期:2005-05-23 发布日期:2010-12-10
  • 通讯作者: 刘孝恒

Self-assembly of ZrO2 Films Templated by Surfactants at the Air-water Interface

LIU Xiao-Heng*,1, WHITE John2, WANG Xina   

  1. (1 Material Chemistry Laboratory, Nanjing University of Science and Technology, Nanjing 210094)
    (2 Research School of Chemistry, Australian National University, Canberra 0200, Australia)
  • Received:2004-11-24 Revised:2005-05-23 Published:2010-12-10
  • Contact: LIU Xiao-Heng

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采用三种阴离子表面活性剂: 十二烷基磺酸钠(SDS), 十二烷基苯磺酸钠(DBS-Na), 十二烷基苯磺酸(DBS-H)作模板, 在空气-水界面上组装ZrO2薄膜. 结果表明, 采用SDS组装的薄膜具有良好的机械强度. 经X射线能量扫描谱原位检测以及X射线衍射(XRD)谱检测证实, 所获薄膜为层状结构, 其层间距在2.70～3.54 nm之间. 利用所建立的层状结构模型解释了各种阴离子表面活性剂组装ZrO2薄膜并控制层间距变化的机理.

关键词: ZrO2薄膜, 空气-水界面, 表面活性剂, 自组装

Three anionic surfactants, sodium dodecyl sulfate (SDS), 4-dodecylbenzenesulfonic acid (DBS-H) and sodium 4-dodecylbenzenesulfonate (DBS-Na) have been readily employed to prepare ZrO2 films at the air-water interface. X-ray reflectivities were used to detect the formation and structure of ZrO2 films. SDS, DBS-H and DBS-Na could all act as templates to assist self-assembly of ZrO2 films and cause different effects on the structures and properties of the films, including d-spacing and strength of the layered films.

Key words: ZrO2 film, air-water interface, surfactant, self-assembly