化学学报 ›› 2001, Vol. 59 ›› Issue (8): 1344-1349. 上一篇    

研究论文

[60]富勒烯与氮杂芳烃叶立德的反应

马声磊;李文玉;张丹维;吴世晖;高翔;吴厚铭;李泳江;王中华   

  1. 复旦大学化学系.上海(200433);中国科学院上海有机化学研究所.上海(200032)
  • 发布日期:2001-08-15

Reactions of [60]Fullerene with azomethine ylides from heteroaromatics

Ma Shenglei;Li Wenyu;Zhang Danwei;Wu Shihui;Gao Xiang;Wu Houming;Li Yongjiang;Wang Zhonghua   

  1. Fudan Univ, Dept Chem.Shanghai(200433);Shanghai Inst Organ Chem., CAS.Shanghai(200032)
  • Published:2001-08-15

[60]富勒烯与乙氧羰基甲基氮杂芳烃叶立德发生1,3-偶极环加成反应,生成[60]富勒烯并吡咯烷衍生物。反应温度对反应有一定的影响。

关键词: 富勒烯, 氮杂环化合物, 芳香烃, 环加成反应, 吡咯烷P, 并吡咯烷P, 化学修饰, 叶立德

Azomethine ylides derived from heteroaromatics was reacted with [60] fullerene to give fulleren-fused pyrrolidine derivatives via a 1,3- dipolar cycloaddition process. The reaction temperature had somehow effects on the reactions.

Key words: FULLERENES, NITROGEN HETEROCYCLICS, AROMATIC HYDROCARBON, CYCLOADDITION REACTION, PYRROLIDINE P, PYRROLIZINE P, CHEMICLAL MODIFICATION

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