化学学报 ›› 2015, Vol. 73 ›› Issue (9): 913-923.DOI: 10.6023/A15030221 上一篇    下一篇

所属专题: 非碳基二维材料

综述

有机或金属-有机二维纳米材料的制备与应用

李绍周a, 黄晓b, 张华c   

  1. a 江苏省有机电子与信息显示重点实验室 南京邮电大学先进材料研究院 南京 210023;
    b 柔性电子重点实验室 先进生物与化学制造协同创新中心 南京工业大学先进材料研究院 南京 211816;
    c 材料科学与工程学院 新加坡南洋理工大学 新加坡 639798
  • 投稿日期:2015-03-31 发布日期:2015-05-21
  • 通讯作者: 黄晓, 张华 E-mail:hzhang@ntu.edu.sg;iamxhuang@njtech.edu.cn
  • 基金资助:

    项目受新加坡教育部基金(ARC 26/13 No. MOE2013-T2-1-034; ARC 19/15, No. MOE2014-T2-2-093; RGT18/13; RG5/13), 新加坡南洋理工大学启动基金(M4081296.070.500000), 南洋理工大学食品安全科研基金(M4081458.070.500000), 新加坡千禧基金, 由新加坡环境与水工业专项办公室(EWI)管理的环境和水技术国家战略研究计划基金, 以及由新加坡总理办公室管理的能源水处理项目(CREATE)基金的支持. 同时, 项目受中国国家自然科学基金(GZ213054; 51322202)以及江苏省自然科学基金(BK20130927)资助.

Preparation and Applications of Two-Dimensional Crystals Based on Organic or Metal-Organic Materials

Li Shaozhoua, Huang Xiaob, Zhang Huac   

  1. a Key Laboratory for Organic Electronics and Information Displays & Institute of Advanced Materials, Jiangsu National Synergistic Innovation Center for Advanced Materials SICAM, Nanjing University of Posts & Telecommunications, Nanjing 210023;
    b Key Laboratory of Flexible Electronics KLOFE & Institute of Advanced Materials IAM, Jiangsu National Synergistic Innovation Center for Advanced Materials SICAM, Nanjing Tech University NanjingTech, Nanjing 211816;
    c School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore
  • Received:2015-03-31 Published:2015-05-21
  • Supported by:

    This work was supported by MOE under AcRF Tier 2 (ARC 26/13, No. MOE2013-T2-1-034; ARC 19/15, No. MOE2014-T2-2-093) and AcRF Tier 1 (RGT18/13, RG5/13), NTU under Start-Up Grant (M4081296.070.500000) and iFood Research Grant (M4081458.070.500000), Singapore Millennium Foundation in Singapore, and the National Natural Science Foundation of China (GZ213054, 51322202) in China, and the Natural Science Foundation of Jiangsu Province (BK20130927). This research grant is supported by the Singapore National Research Foundation under its Environmental & Water Technologies Strategic Research Programme and administered by the Environment & Water Industry Programme Office (EWI) of the PUB. This Research is also conducted by NTU-HUJ-BGU Nanomaterials for Energy and Water Management Programme under the Campus for Research Excellence and Technological Enterprise (CREATE), that is supported by the National Research Foundation, Prime Minister's Office, Singapore.

对石墨烯等二维材料的研究进一步引发了人们对相似结构的其他有机、金属-有机二维层状纳米材料的浓厚兴趣. 这些二维材料由于其优异的化学可剪裁性而受到关注, 预期未来在电子器件、催化和小分子分离等方面具有广泛的用途. 这篇综述系统地介绍了目前制备有机基二维材料的自上而下和自下而上的两大类方法, 总结了有机基二维材料在生物识别、小分子分离和纯化以及电学方面的应用, 最后讨论了有机基二维材料目前在制备和性质改进方面面临的问题和未来可能发展的研究方向.

关键词: 二维材料, 有机晶体, 金属有机骨架材料, 共价有机框架材料

Besides graphene and transitional metal dichalcogenide nanosheets which have aroused tremendous research interest over the last decade, recently, two-dimensional (2D) organic or metal-organic nanosheets have also attracted increasing research interest. These ultrathin nanomaterials possess the long range structural order, the tunable surface properties, and/or controllable porosity, making them promising in a wide range of applications, such as electronics, optoelectronics, catalysis, molecular separation and so on. This review article aims to provide a brief overview on free-standing 2D nanosheets of organic or metal-organic materials that have been reported so far, especially focusing on their synthetic methods and possible applications.

Key words: two dimensional materials, organic crystals, metal organic frameworks, covalent organic frameworks