Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (01): 35-38.DOI: 10.6023/A1105163 Previous Articles     Next Articles

Full Papers

非贵金属Fe催化剂体系催化硝基苯还原羰化反应

张俊, 李云平, 赵邦屯   

  1. 洛阳师范学院化学化工学院, 洛阳 471022
  • 收稿日期:2011-05-16 修回日期:2011-09-14 出版日期:2012-01-14 发布日期:2012-02-25
  • 通讯作者: 赵邦屯 E-mail:zhjosso@sina.com
  • 基金资助:

    国家自然科学基金(No.20872058)资助项目.

Non-noble Metallic Fe Catalyst Systems for the Reductive Carbonylation of Nitrobenzene

Zhang Jun, Li Yunping, Zhao Bangtun   

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022
  • Received:2011-05-16 Revised:2011-09-14 Online:2012-01-14 Published:2012-02-25
  • Supported by:

    Project was supported by the National Natural Science Foundation of China(No.20872058).

A silica-supported chitosan-iron complex SiO2-CS-FeCl3 has a good conversion for reductive carbonylation of nitrobenzene.The high activity and selectivity of the catalyst have been achieved by the synergic effect of Fe-Ni bimetallic system and the effect of polymer protection.

Key words: reductive carbonylation, carbamate, nitrobenzene, chitosan