Acta Chim. Sinica ›› 2017, Vol. 75 ›› Issue (2): 193-198.DOI: 10.6023/A16070337 Previous Articles     Next Articles

Special Issue: 先进电池材料

Communication

高性能Pt纳米管中管电催化剂在甲醇燃料电池中的应用

李奇, 许瀚, 童叶翔, 李高仁   

  1. 生物无机教育部重点实验室 环境与能源化学广东普通高校重点实验室 化学学院中山大学 广州 510275
  • 收稿日期:2016-07-13 修回日期:2016-10-07 出版日期:2017-02-15 发布日期:2017-03-03
  • 通讯作者: 童叶翔,E-mail:sysutong@sina.cn;李高仁,E-mail:ligaoren@mail.sysu.edu.cn E-mail:sysutong@sina.cn;ligaoren@mail.sysu.edu.cn
  • 基金资助:

    项目受国家自然科学基金(51173212)和广东省自然科学基金(S2013020012833)资助.

Pt Tube-in-Tube Arrays as HighPerformance Electrocatalysts for Direct Methanol Fuel Cell

Li Qi, Xu Han, Tong Yexiang, Li Gaoren   

  1. MOE Laboratory of Bioinorganic and Synthetic Chemistry, KLGHEI of Environment and Energy Chemistry, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, China
  • Received:2016-07-13 Revised:2016-10-07 Online:2017-02-15 Published:2017-03-03
  • Contact: 10.6023/A16070337 E-mail:sysutong@sina.cn;ligaoren@mail.sysu.edu.cn
  • Supported by:

    Project supported by the National Natural Science Foundation of China (51173212) and Natural Science Foundation of Guangdong Province (S2013020012833).

The Pt tube-in-tube arrays (TTAs) were designed and synthesized by ZnO template-assisted electrodeposition. As a robust integrated 3D electrocatalyst with high utilization rate and fast transport of electroactive species, the Pt TTAs exhibit a high electrochemically active surface area (ECSA) of 64.9 m2/gPt. Compared with Pt NTAs and commercial Pt/C catalyst, the Pt TTAs exhibit much improved electrocatalytic activity and durability for methanol oxidation. In addition, the Pt TTAs as electrocatalysts exhibit superior CO poisoning tolerance. This work shows the significant progress of Pt-based electrocatalysts with high-performance for direct methanol fuel cells.

Key words: Pt, electrocatalyst, tube-in-tube, methanol oxidation, electroactivity, durability