Acta Chimica Sinica ›› 2024, Vol. 82 ›› Issue (1): 62-74.DOI: 10.6023/A23080392 Previous Articles     Next Articles



林航青a, 马若茹a, 江怡蓝a, 许木榕a, 林洋彭a,b,*(), 杜克钊a,*()   

  1. a福建师范大学 化学与材料学院 福建 福州 350117
    b厦门市环境科学研究院 福建 厦门 361021
  • 投稿日期:2023-08-27 发布日期:2023-10-31
  • 作者简介:

    林航青, 就读于福建师范大学化学与材料学院, 2020级应用化学专业本科生.

    马若茹, 就读于福建师范大学化学与材料学院, 2020级应用化学专业本科生.

    江怡蓝, 就读于福建师范大学化学与材料学院, 2020级应用化学专业本科生.

    许木榕, 就读于福建师范大学化学与材料学院, 2022级化学教育专业本科生.

    林洋彭(1995-), 2023年6月于福建师范大学获得理学博士学位, 同年10月入职厦门市环境科学研究院, 主要研究方向为金属卤化物的设计及应用研究. 至今以第一作者身份在J. Phys. Chem. Lett., Chem. Eng. J., Energy Environ. Mater.等期刊发表6篇SCI论文, 以合作者身份在Angew. Chem. Int. Ed., Nano Lett., Adv. Funct. Mater.等期刊发表15篇SCI论文, 授权中国发明专利两项.

    杜克钊, 2013年博士毕业于中国科学院大学福建物质结构研究所, 相继在新加坡南洋理工大学和美国杜克大学开展博士后研究, 于2018年入职福建师范大学, 主要研究金属卤化物晶态材料的构效关系, 已在J. Am. Chem. Soc., Angew. Chem. Int. Ed.等国际期刊上发表SCI论文90篇左右, 授权专利3项, h-index 29. 主持(含结题)国家基金三项, 获“闽江学者”特聘教授和福建省杰青项目等省部级项目资助.

  • 基金资助:
    项目受国家自然科学基金(22373014); 福建省自然科学基金(2022J06019)

Research Progress of Materials Used for Elemental Halogen Capture

Hangqing Lina, Ruoru Maa, Yilan Jianga, Murong Xua, Yangpeng Lina,b(), Kezhao Dua()   

  1. aCollege of Chemistry and Materials, Fujian Normal University, Fuzhou, Fujian 350117
    bXiamen Institute of Environmental Science, Xiamen, Fujian 361021
  • Received:2023-08-27 Published:2023-10-31
  • Contact: E-mail:;
  • About author:
    These authors contributed equally to this work
  • Supported by:
    National Natural Science Foundation of China(22373014); Natural Science Foundation of Fujian Province(2022J06019)

Elemental halogen, that is fluorine (F2), chlorine (Cl2), bromine (Br2) and iodine (I2), plays an important role in the chemical industry. However, the toxicity, corrosiveness and volatility of elemental halogen pose serious challenges for their safe storage and transportation. Thus, the precuring of these elemental halogen can effectively improve the safety of their usage. Ideal precuring materials for elemental halogen need to meet a variety of requirements, such as stability, selectivity, recyclability, processability, etc., which brings great challenges to the design and synthesis of desired materials. So far, some precuring materials for Cl2 and Br2 have been reported (F2 is not available yet). The summary and review of these materials will help to provide reference for the follow-up materials optimization and design. However, as far as we know, the related review has not been reported yet. Therefore, we give a comprehensive overview of the precuring materials for Cl2 and Br2 including porous organic polymers (POPs), metal-organic frameworks (MOFs), porous organic cages (POCs) and metal halides. The corresponding mechanism and structure-property relationship are discussed in detail. The purpose of this paper is to provide a useful insight into the follow-up materials design for the elemental halogen precuring, and finally get an ideal precuring materials with practical application prospects, so as to improve the usage safety of elemental halogen and reduce the risk of halogen leakage. It is of great significance to environmental protection and sustainable development.

Key words: halogen, adsorption, porous materials, metal halide, redox