Recent Advances of Chiral Hypervalent Iodine Reagents

doi:10.6023/A18110470

Abstract

Hypervalent iodine chemistry has arose as an important field in organic chemistry in the past decades. Hypervalent iodine compounds, with reactivities similarly to transition metals in many different types of transformations, have attracted broad interests in organic community due to their practical advantages in the mild conditions, low costs, environmental benign and low toxicity. Great progresses have been made in this field. Chiral hypervalent iodine reagents or precursors have also been developed and utilized in a variety of asymmetric reactions in a stoichiometric or catalytic way. Important advances have been witnessed in the field of chiral hypervalent iodine chemistry in recent years. However, great limitations still exist. In this review, we have made a summary of different types of chiral hypervalent iodine reagents and precursors according to the characteristics of these compounds and the timeline. It may be helpful for the researchers to better understand the development and limitations of chiral hypervalent iodine chemistry.

Key words: chirality, chiral hypervalent iodine, chiral aryl iodide, asymmetric reaction, catalytic asymmetric synthesis

Cite this article

Cai Qian, Ma Haowen. Recent Advances of Chiral Hypervalent Iodine Reagents[J]. Acta Chim. Sinica, 2019, 77(3): 213-230.

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