Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (5): 588-599.DOI: 10.6023/A20120561 Previous Articles     Next Articles



蔡莉莉a,b, 王静忆a,b, 朱雪峰a,b,c,*(), 杨维慎a,b   

  1. a 中国科学院大连化学物理研究所 催化基础国家重点实验室 大连 116023
    b 中国科学院大学 北京 100049
    c 中国科学院洁净能源创新研究院 大连 116023
  • 投稿日期:2020-12-09 发布日期:2021-01-25
  • 通讯作者: 朱雪峰
  • 作者简介:

    蔡莉莉, 博士, 2019年6月于中国科学院大连化学物理研究所获理学博士学位, 目前在中国科学院大连化学物理研究所从事博士后工作, 主要研究方向为催化膜反应器.

    朱雪峰, 研究员, 博士生导师. 2006年12月于中国科学院大连化学物理研究所获理学博士学位. 主要从事用于气体分离的致密陶瓷膜、膜催化及相关电催化方面的研究.

  • 基金资助:
    项目受国家自然科学基金(22008231); 项目受国家自然科学基金(21776267); 中国科学院洁净能源创新研究院(DNL180203); 辽宁省“兴辽英才”计划(XLYC1801004)

Recent Progress on Mixed Conducting Oxygen Transport Membrane Reactors for Water Splitting Reaction

Lili Caia,b, Jingyi Wanga,b, Xuefeng Zhua,b,c,*(), Weishen Yanga,b   

  1. a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
    b University of Chinese Academy of Sciences, Beijing 100049, China
    c Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, China
  • Received:2020-12-09 Published:2021-01-25
  • Contact: Xuefeng Zhu
  • About author:
  • Supported by:
    National Natural Science Foundation of China(22008231); National Natural Science Foundation of China(21776267); Dalian National Laboratory for Clean Energy (DNL)(DNL180203); LiaoNing Revitalization Talents Program(XLYC1801004)

Catalytic membrane reactors based on mixed conducting oxygen transport membranes (OTMs) have the ability to integrate reaction and separation, and thus simplify the chemical process by coupling oxygen supplying reaction, oxygen separation and oxygen consumption reaction into a single unit. In recent years, more and more attentions have been paid to the mixed conducting OTM reactors for water splitting reaction owing to their applications for preparation and separation of hydrogen. In this article, we summarize the recent progress on mixed conducting OTM reactors for water splitting reaction, including the effects of membrane materials, catalysts and operation conditions on the water splitting involved membrane reactors. Meanwhile, the current existing problems in the above aspects are analyzed, and the future development of membrane materials, membrane structures and catalysts in this field is prospected. We wish this paper will be helpful for the development of the water splitting in membrane reactors.

Key words: hydrogen, oxygen transport membrane, water splitting, membrane material, catalyst