Acta Chimica Sinica ›› 2024, Vol. 82 ›› Issue (2): 213-225.DOI: 10.6023/A23100445 Previous Articles Next Articles
Special Issue: 庆祝《化学学报》创刊90周年合辑
Review
投稿日期:
2023-10-10
发布日期:
2024-01-04
作者简介:
李雅宁, 上海科技大学/中国科学院上海有机化学研究所2019级联合培养博士. 2019年本科毕业于河南大学. 目前研究方向为光诱导的可控自由基聚合. |
王晓艳, 中国科学院上海有机化学研究所副研究员. 2010年本科毕业于东北林业大学. 2015年在中国科学院长春应用化学研究所取得博士学位. 随后在中国科学院上海有机化学研究所金属有机化学实验室/南开大学化学系进行博士后的研究工作. 2017年正式加入上海有机所金属有机化学国家重点实验室, 开展新型过渡金属催化剂、可控自由基聚合及可控烯烃配位聚合等方面的研究. |
唐勇, 中国科学院上海有机化学研究所研究员. 1986年本科毕业于四川师范大学; 1992年和1996年先后在中国科学院上海有机化学研究所获得硕士和博士学位. 1996年至1999年先后在美国科罗拉多州立大学和美国乔治城大学从事博士后研究; 1999年5月入职上海有机化学研究所, 2000年1月, 担任上海有机化学研究所“百人计划”项目研究员, 2015年当选中国科学院院士. 主要从事金属有机化学和高分子化学研究, 包括: 不对称催化、烯烃聚合催化剂的设计、合成与应用、叶立德化学以及天然产物全合成等. |
基金资助:
Yaning Lia,b, Xiaoyan Wanga(), Yong Tanga
Received:
2023-10-10
Published:
2024-01-04
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Yaning Li, Xiaoyan Wang, Yong Tang. The Regulation of Stereoselectivity in Radical Polymerization★[J]. Acta Chimica Sinica, 2024, 82(2): 213-225.
Run | Ligand | T/℃ | t/h | Conv./% | Mn (×103) | Đ | rr/% |
---|---|---|---|---|---|---|---|
1 | L1 | 25 | 12 | 75 | 11.9 | 1.1 | 68 |
2 | L2 | 25 | 12 | 59 | 9.90 | 1.1 | 72 |
3 | L3 | 25 | 12 | 93 | 9.96 | 1.1 | 72 |
4 | L1 | 0 | 36 | 55 | 11.1 | 1.3 | 71 |
5 | L2 | 0 | 36 | 49 | 12.1 | 1.1 | 74 |
6 | L3 | 0 | 36 | 75 | 11.3 | 1.1 | 78 |
7 | L1 | –40 | 60 | 24 | 15.8 | 1.2 | 79 |
8 | L2 | –40 | 60 | 10 | 9.54 | 1.3 | 83 |
9 | L3 | –40 | 60 | 25 | 13.8 | 1.3 | 88 |
10 | L1 | –60 | 72 | 10 | 42.0 | 1.4 | 82 |
11 | L2 | –60 | 72 | trace | — | — | — |
12 | L3 | –60 | 72 | 12 | 32.2 | 1.4 | 92 |
Run | Ligand | T/℃ | t/h | Conv./% | Mn (×103) | Đ | rr/% |
---|---|---|---|---|---|---|---|
1 | L1 | 25 | 12 | 75 | 11.9 | 1.1 | 68 |
2 | L2 | 25 | 12 | 59 | 9.90 | 1.1 | 72 |
3 | L3 | 25 | 12 | 93 | 9.96 | 1.1 | 72 |
4 | L1 | 0 | 36 | 55 | 11.1 | 1.3 | 71 |
5 | L2 | 0 | 36 | 49 | 12.1 | 1.1 | 74 |
6 | L3 | 0 | 36 | 75 | 11.3 | 1.1 | 78 |
7 | L1 | –40 | 60 | 24 | 15.8 | 1.2 | 79 |
8 | L2 | –40 | 60 | 10 | 9.54 | 1.3 | 83 |
9 | L3 | –40 | 60 | 25 | 13.8 | 1.3 | 88 |
10 | L1 | –60 | 72 | 10 | 42.0 | 1.4 | 82 |
11 | L2 | –60 | 72 | trace | — | — | — |
12 | L3 | –60 | 72 | 12 | 32.2 | 1.4 | 92 |
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