Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (4): 513-519.DOI: 10.6023/A20120562 Previous Articles Next Articles
Article
焦桐a, 许雪莲a, 张磊a,*(), 翁幼云b, 翁玉冰b, 高志贤a
投稿日期:
2020-12-10
发布日期:
2021-02-05
通讯作者:
张磊
基金资助:
Tong Jiaoa, Xue-lian Xua, Lei Zhanga,*(), You-yun Wengb, Yu-bing Wengb, Zhi-xian Gaoa
Received:
2020-12-10
Published:
2021-02-05
Contact:
Lei Zhang
About author:
Supported by:
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Tong Jiao, Xue-lian Xu, Lei Zhang, You-yun Weng, Yu-bing Weng, Zhi-xian Gao. Research on CuO/CeO2-ZrO2/SiC Monolithic Catalysts for Hydrogen Production by Methanol Steam Reforming[J]. Acta Chimica Sinica, 2021, 79(4): 513-519.
催化剂a | 比表面积/ (m2•g–1) | 孔容/ (cm3•g–1) | Cu比表面积b/ (m2•g–1) | 产氢速率c/ (L•m–3•s–1) |
---|---|---|---|---|
a | 98.3 | 0.32 | — | — |
b | 98.3 | 0.31 | 4.8 | 631 |
c | 94.6 | 0.30 | 5.8 | 1556 |
d | 69.5 | 0.26 | 5.6 | 1418 |
e | 63.2 | 0.21 | 5.1 | 1407 |
催化剂a | 比表面积/ (m2•g–1) | 孔容/ (cm3•g–1) | Cu比表面积b/ (m2•g–1) | 产氢速率c/ (L•m–3•s–1) |
---|---|---|---|---|
a | 98.3 | 0.32 | — | — |
b | 98.3 | 0.31 | 4.8 | 631 |
c | 94.6 | 0.30 | 5.8 | 1556 |
d | 69.5 | 0.26 | 5.6 | 1418 |
e | 63.2 | 0.21 | 5.1 | 1407 |
催化剂 | 峰位置/℃ | 面积占比/% | ||
---|---|---|---|---|
α峰 | β峰 | α峰 | β峰 | |
2%CuO/CeO2-ZrO2/SiC | 137 | 192 | 30.2% | 69.8% |
5%CuO/CeO2-ZrO2/SiC | 137 | 194 | 24.6% | 75.4% |
10%CuO/CeO2-ZrO2/SiC | 138 | 197 | 14.3% | 85.7% |
20%CuO/CeO2-ZrO2/SiC | 138 | 208 | 9.0% | 91.0% |
催化剂 | 峰位置/℃ | 面积占比/% | ||
---|---|---|---|---|
α峰 | β峰 | α峰 | β峰 | |
2%CuO/CeO2-ZrO2/SiC | 137 | 192 | 30.2% | 69.8% |
5%CuO/CeO2-ZrO2/SiC | 137 | 194 | 24.6% | 75.4% |
10%CuO/CeO2-ZrO2/SiC | 138 | 197 | 14.3% | 85.7% |
20%CuO/CeO2-ZrO2/SiC | 138 | 208 | 9.0% | 91.0% |
催化剂 | Ce3+含量占比/% | Cu+含量占比/% |
---|---|---|
2%CuO/CeO2-ZrO2/SiC | 9.9 | 67.1 |
5%CuO/CeO2-ZrO2/SiC | 14.5 | 70.5 |
10%CuO/CeO2-ZrO2/SiC | 12.3 | 67.3 |
20%CuO/CeO2-ZrO2/SiC | 11.2 | 59.2 |
催化剂 | Ce3+含量占比/% | Cu+含量占比/% |
---|---|---|
2%CuO/CeO2-ZrO2/SiC | 9.9 | 67.1 |
5%CuO/CeO2-ZrO2/SiC | 14.5 | 70.5 |
10%CuO/CeO2-ZrO2/SiC | 12.3 | 67.3 |
20%CuO/CeO2-ZrO2/SiC | 11.2 | 59.2 |
催化剂 | T/℃ | H2O/CH3OH | GHSV/ h–1 | 产氢速率/ (L•m–3•s–1) |
---|---|---|---|---|
5%CuO/CeO2-ZrO2/SiC | 360 | 1.2:1 | 4840 | 1556 |
10%Cu/γ-Al@MMO[ | 300 | 1.2:1 | 1760 | 721 |
CuO/CeO2-R[ | 240 | 1.2:1 | 1760 | 631 |
CuZnCeZr[ | 240 | 1.2:1 | 2640 | 1020 |
Zn1Ce1Zr9Ox[ | 400 | 1.4:1 | 2955 | 1135 |
Zn5Ce1Zr9Ox[ | 400 | 1.4:1 | 2955 | 476 |
催化剂 | T/℃ | H2O/CH3OH | GHSV/ h–1 | 产氢速率/ (L•m–3•s–1) |
---|---|---|---|---|
5%CuO/CeO2-ZrO2/SiC | 360 | 1.2:1 | 4840 | 1556 |
10%Cu/γ-Al@MMO[ | 300 | 1.2:1 | 1760 | 721 |
CuO/CeO2-R[ | 240 | 1.2:1 | 1760 | 631 |
CuZnCeZr[ | 240 | 1.2:1 | 2640 | 1020 |
Zn1Ce1Zr9Ox[ | 400 | 1.4:1 | 2955 | 1135 |
Zn5Ce1Zr9Ox[ | 400 | 1.4:1 | 2955 | 476 |
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