Preparation and Capacity Fading Mechanism of Tin Thin Film as Anode of Lithium-ion Battery

Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (2): 165-169. Previous Articles Next Articles

Original Articles

锂离子电池薄膜锡负极材料的制备及容量衰减机理研究

樊小勇¹, 庄全超¹, 许金梅¹, 江宏宏¹, 黄令¹, 董全峰¹,2, 孙世刚*^,1

(¹固体表面物理化学国家重点实验室厦门大学化学化工学院化学系厦门 361005)
(²厦门大学宝龙电池研究所厦门 361005)

投稿日期:2005-12-28 修回日期:2006-04-20 发布日期:2007-01-28
通讯作者: 孙世刚

Preparation and Capacity Fading Mechanism of Tin Thin Film as Anode of Lithium-ion Battery

FAN Xiao-Yong¹; ZHUANG Quan-Chao¹; XU Jin-Mei¹; JIANG Hong-Hong¹; HUANG Ling¹; DONG Quan-Feng¹,2; SUN Shi-Gang*^,1

(¹State Key Lab for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005)
(²Xiamen University-Powerlong Battery Research Institute, Xiamen 361005)

Received:2005-12-28 Revised:2006-04-20 Published:2007-01-28
Contact: SUN Shi-Gang

Abstract

Tin thin film coated on Cu substrate as anode of lithium-ion battery was prepared by electroplating. Its structure and properties were characterized and studied by X-ray diffration, scanning electron microscopy, cyclic voltammetry, charging/discharging test and AC impedence method. XRD patterns indicate that the tin thin film exhibits a structure of tetragonal crystal. The first discharge and charge capacities of the tin thin film electrode were determined to be 709 and 561 mAh•g^－1, respectively. Cyclic voltammetric results illustrated that multi-phase changes occurred during the lithiation and delithiation. Elec-trochemical impedance spectroscopy (EIS) results indicated that SEI film was begun to form on the surface of tin thin film electrode at 1.2 V, and then break down below 0.4 V because of large volume expansion. SEM investigations revealed that the tin thin film electrode appeared serious cracks after 30 charging and discharging cycles.

Key words: lithium-ion battery, anode material, tin thin film, electroplating

Cite this article

FAN Xiao-Yong; ZHUANG Quan-Chao; XU Jin-Mei; JIANG Hong-Hong; HUANG Ling; DONG Quan-Feng^1,2; SUN Shi-Gang*^,1. Preparation and Capacity Fading Mechanism of Tin Thin Film as Anode of Lithium-ion Battery[J]. Acta Chimica Sinica, 2007, 65(2): 165-169.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Xiaoyu Gu, Jin Li, Qian Sun, Chaoyang Wang. Microcalorimetry Analysis of Thermal Runaway Process in Lithium-ion Batteries [J]. Acta Chimica Sinica, 2024, 82(2): 146-151.
[2]	Jia Yanggang, Chen Shijie, Shao Xia, Cheng Jie, Lin Na, Fang Daolai, Mao Aiqin, Li Canhua. Preparation and High-performance Lithium-ion Storage of Cobalt-free Perovskite High-entropy Oxide Anode Materials [J]. Acta Chimica Sinica, 2023, 81(5): 486-495.
[3]	Wanying Chang, Yingying Tan, Jingyi Wu, Yingjie Liu, Jinhai Cai, Chunyan Lai. Study on the Properties of Polyethylene Oxide Based Solid State Electrolyte Enhanced by Three-Dimensional Structured Li_6.28La₃Zr₂Al_0.24O₁₂ [J]. Acta Chimica Sinica, 2023, 81(12): 1708-1715.
[4]	Yalan Zhang, Zhixiang Yuan, Hao Zhang, Jianjun Zhang, Guanglei Cui. Research Progress of High-energy-density Solid-state Lithium Ion Batteries Employing Ni-rich Ternary Cathodes [J]. Acta Chimica Sinica, 2023, 81(12): 1724-1738.
[5]	Shuang Zhang, Chengfei Yang, Yubo Yang, Ningning Feng, Gang Yang. Electrochemical Behaviors of Li_xMO (x=0.79, 0.30, 0.08; M=Ni/Co/Mn) Recycled from Spent Li-ion Batteries as Cathodic Catalyst for Lithium-Oxygen Battery [J]. Acta Chimica Sinica, 2022, 80(9): 1269-1276.
[6]	Wenchao Bi, Linfeng Zhang, Jian Chen, Ruixue Tian, Hao Huang, Man Yao. Lithiation Mechanism and Performance of Monoclinic ZnP₂ Anode Materials [J]. Acta Chimica Sinica, 2022, 80(6): 756-764.
[7]	Shouxiao Chen, Junke Liu, Weichen Zheng, Guozhen Wei, Yao Zhou, Juntao Li. Electron/ion Conductor Double-coated LiNi_0.8Co_0.1Mn_0.1O₂ Li-ion Battery Cathode Material and Its Electrochemical Performance [J]. Acta Chimica Sinica, 2022, 80(4): 485-493.
[8]	Kai Qiu, Mingxia Yan, Shouwang Zhao, Shengli An, Wei Wang, Guixiao Jia. Theoretical Study on the Structural Stability and Oxygen Ion Oxidation of Al-doped Lithium-ion Battery Layered Cathode Li(Li_0.17Ni_0.17Al_0.04Fe_0.13Mn_0.49)O₂ [J]. Acta Chimica Sinica, 2021, 79(9): 1146-1153.
[9]	Ping Xu, Xihua Zhang, En Ma, Fu Rao, Chunwei Liu, Peifan Yao, Zhi Sun, Jingwei Wang. Selective Recovery of Lithium from Spent Lithium-ion Batteries Synergized by Carbon and Sulfur Elements [J]. Acta Chimica Sinica, 2021, 79(8): 1073-1081.
[10]	Zhi Chang, Yu Qiao, Huijun Yang, Han Deng, Xingyu Zhu, Ping He, Haoshen Zhou. Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes [J]. Acta Chimica Sinica, 2021, 79(2): 139-145.
[11]	Wang Shan, Fan Xiaoyong, Cui Yu, Gou Lei, Wang Xingang, Li Donglin. Three-dimensional Porous Current Collector for Lithium Storage Enhancement of NiO Electrode [J]. Acta Chim. Sinica, 2019, 77(6): 551-558.
[12]	Wang Xiaoyu, Zhang Yu, Ma Lei, Wei Liangming. Recent Development on Binders for Silicon-Based Anodes in Lithium-Ion Batteries [J]. Acta Chim. Sinica, 2019, 77(1): 24-40.
[13]	Wang Ling, Yang Guorui, Wang Jianan, Wang Silan, Peng Shengjie, Yan Wei. Research Progress on Electrospun Materials for Sodium-Ion Batteries [J]. Acta Chim. Sinica, 2018, 76(9): 666-680.
[14]	Deng Bangwei, Sun Daming, Wan Qi, Wang Hao, Chen Tao, Li Xuan, Qu Meizhen, Peng Gongchang. Review of Electrolyte Additives for Ternary Cathode Lithium-ion Battery [J]. Acta Chim. Sinica, 2018, 76(4): 259-277.
[15]	He Qian, Zhang Chong, Li Xiao, Wang Xue, Mu Pan, Jiang Jiaxing. Pyrene-Based Conjugated Microporous Polymer as High Performance Electrode for Lithium-Ion Batteries [J]. Acta Chim. Sinica, 2018, 76(3): 202-208.

锂离子电池薄膜锡负极材料的制备及容量衰减机理研究

Preparation and Capacity Fading Mechanism of Tin Thin Film as Anode of Lithium-ion Battery

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments