A conventional wire-like plasma enhanced and spread by pulsed microwave was used to study the oxidative coupling and reforming of CH_4 with CO_2 to CO, C_2H_2, C_2H_4 and H_2. Under the conditions of atmospheric pressure, flow rate of 200 mL/min (CH_4/CO_2 = 1.5:1), peak microwave power of 120 W and pulse duty factor of 100/100 ms, conversions of CH_4 and CO_2 were 70.8% and 68.8%, respectively; selectivities of CO, C_2H_2, C_2H_4 were 75%, 17.8% and 4.1%, respectively, and there was no carbon deposits. Ratio of H_2/CO increased with increasing CH_4 concentration in the feed gas, and a H_2/CO ratio of 2 could be obtained at a ratio 2:1 of CH_4 to CO_2, which is acceptable for Fischer-Tropsch and other synthesis processes. The energy efficiency of the pulsed microwave plasma was obviously improved. We suggested that this enhanced pulsed plasma is useful for oxidative coupling and reforming of CH_4 with CO_2 in C1 chemistry.

Key words: OXIDATION, COUPLED, REFORMING, METHANE, CARBON DIOXIDE, PLASMA