Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (3): 354-358. Previous Articles     Next Articles

Original Articles

纳米沸石胶体化学性质的研究

王兴东;王亚军;杨武利;董安钢;任楠;谢在库;唐颐   

  1. 复旦大学;中国石油化工总公司上海石油化工研究院
  • 发布日期:2003-03-15

Investigation of the Colloidal Properties of Nanozeolites

Wang Xingdong;Wang Yajun;Yang Wuli;Dong Angang;Ren Nan;Xie Zaiku;Tang Yi   

  1. Department of Chemistry & Shangshai Key Laboratory of Molecular Catalysis and Innovative Materials,Fudan University;Department of Macromolecular Science & Key Laboratory of Molecular Engineering of Polymers,Fudan University;Shanghai Research Institute of Petrochemical Technology,SINOPEC
  • Published:2003-03-15

In this paper, the colloidal properties of nanosized zeolites with MFI and BEA topology structure were investigated. It is found thatξ potential of nanosized zeolites varied with the change of zeolite structures and composition. The influences of salt concentration and pH value on theξpotential of the nanosized zeolites have been studied. With the increase of the salt concentration, theξ potential gradually decreased and even possessed opposite charges. The effects ofξpotential on the colloidal aggregation and stability are also detected. A cretainξpotential is necessary to stabilize the zeolite colloid, while too lowξpotential may bring on aggregation of the colloid. At stuitabie temperature, nanozeolite can be self- assembled by capillary force to form transparent self-standing fibers. The crystal size significantly influences the character of the products. The zeolites with smaller crystal size are rather apt to form long, dense and transparent zeolite fibers.

Key words: NANOPHASE MATERIALS, ZEOLITE, COLLOID, ELECTRIC POTENTIAL, ELECTROLYTE

CLC Number: