Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (09): 1095-1103.DOI: 10.6023/A1110111 Previous Articles     Next Articles

Full Papers

新型螺吡喃化合物的合成及应用研究

谭春斌a, 赵泽琳a, 高峻a, 雷景新b   

  1. a. 四川大学化学工程学院 成都 610065;
    b. 四川大学高分子材料工程国家重点实验室 成都 610065
  • 收稿日期:2011-10-11 修回日期:2012-01-12 出版日期:2012-05-14 发布日期:2012-01-31
  • 通讯作者: 高峻

Synthesis of Novel Photochromic Spiropyran Compounds and Their Application Study

Tan Chunbina, Zhao Zelina, Gao Juna, Lei Jingxinb   

  1. a. Chemical Engineering Institute of Sichuan University, Chengdu 610065;
    b. The State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065
  • Received:2011-10-11 Revised:2012-01-12 Online:2012-05-14 Published:2012-01-31

The several kinds of new novel spiropyran (SP) compounds were first designed and synthesized. The structures of these target compounds were characterized by 1H NMR, IR and MS tests. The photochromic properties of target compounds and their influencing factors were studied, and the applications of SP1 on the polymer materials field were initially investigated. The results show that λmax in UV-vis absorption spectra will shift to longer wavelengths as the result of benzopyran ring linked with strong electrowithdrawing groups; the thermal fade rate is slower with N atom linked with flexible long group; SP1 has good fatigue resistance compared with the other kinds of the target compounds. The fading rate of both SP-g-hPMMA and SP-m-PMMA are obviously slower than that of SP1. The tensile strength and elongation at break of SP-g-hPMMA and SP-m-PMMA were almost unchanged compared with that of PMMA. It is expected that SP-g-hPMMA and SP-m-PMMA will be applied in the field of polymer photochromic materials.

Key words: spiropyran, photochromism compound, synthesis, PMMA