Luminescent Polymers Containing Unconventional Chromophores

doi:10.6023/A13010071

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (07): 979-990.DOI: 10.6023/A13010071 Previous Articles Next Articles

Review

含非典型性生色团的发光聚合物

黄田^a, 汪昭旸^a, 秦安军^a, 孙景志^a, 唐本忠^b

a 浙江大学高分子合成与功能构造教育部重点实验室高分子科学与工程学系杭州 310027;
b 香港科技大学化学系香港九龙清水湾

投稿日期:2013-01-15 发布日期:2013-03-15
通讯作者: 孙景志, E-mail: sunjz@zju.edu.cn, Tel.: 0571-87953734, Fax: 0571-87953734;唐本忠, tanbenz@ust.hk, Tel.: 0852-23587375; Fax: 0852-23581594. E-mail:sunjz@zju.edu.cn; tanbenz@ust.hk
作者简介:黄田, 女, 汉族. 2010 年7 月毕业于中南民族大学材料化学系, 获工学学士学位. 同年9 月进入浙江大学高分子科学与工程学系攻读硕士学位, 开展含非典型性荧光生色团的超支化聚酰胺胺的合成与发光机理研究.
基金资助:
项目受国家自然科学基金(No. 21074113)和科技部973项目(No. 2013CB834704)资助

Luminescent Polymers Containing Unconventional Chromophores

Huang Tian^a, Wang Zhaoyang^a, Qin Anjun^a, Sun Jingzhi^a, Tang Benzhong^b

a MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China;
b Department of Chemistry, Institute of Molecular Functional Materials, the Institute for Advanced Study (IAS), The Hong Kong University of Science & Technology, Clear Water Bay, Kowloon, Hong Kong, China

Received:2013-01-15 Published:2013-03-15
Contact: 10.6023/A13010071 E-mail:sunjz@zju.edu.cn; tanbenz@ust.hk
Supported by:
Projects supported by the National Natural Science Foundation of China (No. 21074113) and the Ministry of Science and Technology of China (No. 2013CB834704).

Luminescent polymers are referred to as conjugated polymers, which are constructed by p-aromatic building blocks functioning as emitting units. But in recent years, it has been found that a few kinds of polymers only containing auxochromophores or unconventional chromophores such as aliphatic tertiary amine, carbonyl, ester, and amide demonstrate strong luminescence under proper conditions. Poly(amido amine) (PAMAM) dendrimers and hyperbranched poly(amido amine)s are the first reported and most investigated luminescent polymers containing unconventional chromophores. Lately, this kind of polymers have been extended to hyperbranched poly(amino ester)s (hb-PAEs), hyperbranched poly(ether amide)s (hb-PEAs), and polyurea dendrimers (PUREs) containing tertiary amine moieties. The luminogen of PAMAMs, hb-PAEs, hb-PEAs and PUREs is associated with the N-branched tertiary amine moiety and the oxidation of the tertiary amine is assigned to the emitting source. Meanwhile, some distinct polymers had been also reported to be luminescent. Poly[(maleic anhydride)-alt-(vinyl acetate)], polyisobutene succinic anhydrides, glycodynamer analogues of poly(acrylhydrazone)s and multiblock polymer derived by poly(trithiocarbonate) mediated reversible addition-fragmentation chain transfer (RAFT) polymerization of N-isopropyl-acrylamide. A common feature of these polymers is that only carbonyl and ester groups rather than tertiary amine are involved in the polymer structure. Aggregation of multiple carbonyl groups induced emission is usually adopted to explain the mechanism of the emission, and the interaction between carbonyl and phenyl groups was also used to explain the unconventional emission.

Key words: chromophore, tertiary amine, carbonyl, fluorescence, hyperbranched poly(amido amine)

Cite this article

Huang Tian, Wang Zhaoyang, Qin Anjun, Sun Jingzhi, Tang Benzhong. Luminescent Polymers Containing Unconventional Chromophores[J]. Acta Chimica Sinica, 2013, 71(07): 979-990.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Dong, J. H.; Zhang, X.; Wang, L. X. Frontier and Prospect of Polymer Science, Science Press, Beijing, 2011, pp. 409～485. (董建华, 张希, 王立祥, 高分子科学学科前沿与展望, 科学出版社, 北京, 2011, pp. 409～485.)
[2] Demas, J. N.; Crosby, G. A. J. Phys. Chem. 1971, 75, 991.
[3] Varnavski, O.; Ispasoiu, R. G.; Balogh, L.; Tomalia, D.; Goodson III, T. J. Chem. Phys. 2001, 114, 1962.
[4] Zheng, J.; Petty, J. T.; Dickson, R. M. J. Am. Chem. Soc. 2003, 125, 7780.
[5] Lee, W. I.; Bae, Y.; Bard, A. J. J. Am. Chem. Soc. 2004, 126, 8358.
[6] Wang, D.; Imae, T. J. Am. Chem. Soc. 2004, 126, 13204.
[7] Cao, L.; Yang, W. L.; Wang, C. C.; Fu, S. K. J. Macromol. Sci. Part A: Pure Appl. Chem. 2007, 44, 417.
[8] Wang, D.; Imae, T.; Miki, M. J. Colloid Interface Sci. 2007, 306, 222.
[9] Chu, C.-C.; Imae, T. Macromol. Rapid Commun. 2009, 30, 89.
[10] Pastor-Pe′rez, L.; Chen, Y.; Shen, Z.; Lahoz, A.; Stiriba, S.-E. Macromol. Rapid Commun. 2007, 28, 1404.
[11] Lin, S.-Y.; Wu, T.-H.; Jao, Y.-C.; Liu, C.-P.; Lin, H.-Y.; Lo, L.-W.; Yang, C.-S. Chem. Eur. J. 2011, 17, 7158.
[12] Saravanan, G.; Imae, T. J. Nanosci. Nanotechnol. 2011, 11, 4838.
[13] Tsai, Y.-J.; Hu, C.-C.; Chu, C.-C.; Imae, T. Biomacromolecules 2011, 12, 4283.
[14] Imae, T.; Hamaguchi, S. Carbohydr. Polym. 2012, 88, 352.
[15] Yang, W.; Pan, C.-Y. Macromol. Rapid Commun. 2009, 30, 2096.
[16] Yang, W.; Pan, C.-Y.; Luo, M.-D.; Zhang, H.-B. Biomacromolecules 2010, 11, 1840.
[17] Yang, W.; Pan, C.-Y.; Liu, X.-Q.; Wang, J. Biomacromolecules 2011, 12, 1523.
[18] You, Y.-Z.; Yu, Z.-Q.; Cui, M.-M.; Hong, C.-Y. Angew. Chem. Int. Ed. 2010, 49, 1099.
[19] Chen, Y.; Zhou, L.; Pang, Y.; Huang, W.; Qiu, F.; Jiang, X.; Zhu, X. Y.; Yan, D.; Chen, Q. Bioconjugate Chem. 2011, 22, 1162.
[20] Wu, D. C.; Liu, Y.; He, C. B.; Goh, S. H. Macromolecules 2005, 38, 9906.
[21] Wu, D. C.; Liu, Y.; Chen, L.; He, C. B.; Chung, T. S.; Goh, S. H. Macromolecules 2005, 38, 5519.
[22] Sun, M.; Hong, C.-Y.; Pan, C.-Y. J. Am. Chem. Soc. 2012, 134, 20581.
[23] Halpern, A. M.; Wryzykowska, K. J. Photochem. 1981, 15, 147.
[24] Liu, Y.; Gao, J.-W.; Liu, H.-W.; Li, Y.-S. Macromolecules 2009, 42, 3237.
[25] Restani, R. B.; Morgado, P. I.; Ribeiro, M. P.; Correia, I. J.; Aguiar-Ricardo, A.; Bonifácio, V. D. B. Angew. Chem. Int. Ed. 2012, 51, 5162.
[26] Hong, Y.; Lam, J. W. Y.; Tang, B. Z. Chem. Soc. Rev. 2011, 40, 5361.
[27] Zhang, S.; Qin, A.; Sun, J. Z.; Tang, B. Z. Prog. Chem. 2011, 23, 623.
[28] Hong, Y. N.; Lam, J. W. Y.; Tang, B. Z. Chem. Commun. 2009, 4332.
[29] Xing, C. M.; Lam, J. W. Y.; Qin, A. J.; Dong, Y. Q.; Haussler, M.; Yang, W. T.; Tang, B. Z. Polym. Mater. Sci. Eng. 2007, 96, 418.
[30] Qin, A.; Lam, J. W. Y.; Tang, B. Z. Prog. Polym. Sci. 2012, 37, 182.
[31] Pucci, A.; Rausa, R.; Ciardelli, F. Macromol. Chem. Phys. 2008, 209, 900.
[32] Ruff, Y.; Lehn, J.-M. Angew. Chem. Int. Ed. 2008, 47, 3556.
[33] Gao, L.; Fei, J. B.; Zhao, J.; Cui, W.; Cui, Y.; Li, J. B. Chem. Eur. J. 2012, 18, 3185.
[34] Chen, Y.; Spiering, A. J. H.; Karthikeyan, S.; Peters, G. W. M.; Meijer, E. W.; Sijbesma, R. P. Nat. Chem. 2012, 4, 559.
[35] Yan, J.-J.; Wang, Z.-K.; Lin, X.-S.; Hong, C.-Y.; Liang, H.-J.; Pan, C.-Y.; You, Y.-Z. Adv. Mater. 2012, 24, 5617.

含非典型性生色团的发光聚合物

Luminescent Polymers Containing Unconventional Chromophores

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jian Zheng, Jin-Hong Lin, Ji-Chang Xiao. Difluorocarbene-based Trifluoromethylthiolation of Aryl and Alkenyl Iodides [J]. Acta Chimica Sinica, 2024, 82(2): 115-118.
[2]	Yinuo Wang, Shiyang Shao, Lixiang Wang. Recent Advances in Multiple Resonance Organic/Polymer Fluorescent Materials with Narrowband Emission^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1202-1214.
[3]	Fengjie Ge, Kaizhi Zhang, Qingpeng Cao, Hui Xu, Tao Zhou, Wenhao Zhang, Xinxin Ban, Xiaobo Zhang, Na Li, Peng Zhu. Design, Synthesis and Electroluminescence Performance of Flexible Fluorenyl Block Delayed Fluorescence Dimers [J]. Acta Chimica Sinica, 2023, 81(9): 1157-1166.
[4]	Feida Che, Xiaoming Zhao, Xin Zhang, Qi Ding, Xin Wang, Ping Li, Bo Tang. Fluorescence Imaging of Active Molecules Associated with Depression^★ [J]. Acta Chimica Sinica, 2023, 81(9): 1255-1264.
[5]	Xiao Wang, Xingwen Wang, Lehui Xiao. Nanocatalytic Mechanisms Investigated by Single Molecule Fluorescence Imaging at the Single-Particle Level [J]. Acta Chimica Sinica, 2023, 81(8): 1002-1014.
[6]	Hongyue Wu, Rui Guo, Hanwen Chi, Yonghe Tang, Sirui Song, Enxiang Ge, Weiying Lin. Viscosity Fluorescent Probes Based on Quinoline Group and Its Applications [J]. Acta Chimica Sinica, 2023, 81(8): 905-911.
[7]	Wenshan Zheng, Guanbin Gao, Hao Deng, Taolei Sun. Room Temperature Synthesis and Near-infrared Fluorescence Performance Optimization of Ag₂Se@Ag₂S Core-shell Quantum Dots [J]. Acta Chimica Sinica, 2023, 81(7): 763-770.
[8]	Zhenyu Liu, Junfeng Rao, Shoujia Zhu, Bingyang Wang, Fan Yu, Quanyou Feng, Linghai Xie. Research Progress of Solution-Processed Self-Host Thermally Activated Delayed Fluorescence Materials [J]. Acta Chimica Sinica, 2023, 81(7): 820-835.
[9]	Yinfeng Wang, Meng Li, Chuanfeng Chen. Chiral Triptycene-Based Red Thermally Activated Delayed Fluorescence Polymers and Their Organic Light-Emitting Diodes^★ [J]. Acta Chimica Sinica, 2023, 81(6): 588-594.
[10]	Li Liu, Gang Zheng, Guoqiang Fan, Hongguang Du, Jiajing Tan. Research Progress in Organic Reactions Involving 4-Acyl/Carbamoyl/Alkoxycarbonyl Substituted Hantzsch Esters [J]. Acta Chimica Sinica, 2023, 81(6): 657-668.
[11]	Mingliang Han, Lihua Xu. Progress on the Transition Metal-catalyzed Cross-coupling Reaction of Thioesters [J]. Acta Chimica Sinica, 2023, 81(4): 381-392.
[12]	Xin Lv, Yi Wu, Boran Zhang, Wei Guo. Design, Synthesis and Photodynamic Therapy of a H₂O₂-Activatable Near Infrared Borondipyrromethene （BODIPY） Photosensitizer [J]. Acta Chimica Sinica, 2023, 81(4): 359-370.
[13]	Shaoqin Zhang, Meiqing Li, Zhongjun Zhou, Zexing Qu. Theoretical Study on the Multiple Resonance Thermally Activated Delayed Fluorescence Process [J]. Acta Chimica Sinica, 2023, 81(2): 124-130.
[14]	Yanqin Huang, Lijun Li, Shupei Yang, Rui Zhang, Xingfen Liu, Quli Fan, Wei Huang. HA-AuNPs/FDF for Highly Sensitive Detection of Hyaluronidase, Tumor-targeting Fluorescence Cell Imaging and Phototherapy [J]. Acta Chimica Sinica, 2023, 81(12): 1687-1694.
[15]	Li Sun, Yajing Wang, Tao Li, Yingshu Guo, Shusheng Zhang. Au Nanocages Probes for Mitochondrial Imaging and Photothermal Damage Cells^★ [J]. Acta Chimica Sinica, 2023, 81(10): 1301-1310.