Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-Naphthalenedicarboxylate)

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (9): 901-904. Previous Articles Next Articles

新型三维锰(Ⅱ)配位聚合物[Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF(NDC=2,6-萘二酸)的合成与表征

周国强, 陈金喜, 陈珍霞, 田运齐, 郁挺, 翁林红, 赵东元

复旦大学化学系,分子催化与创新材料实验室,上海,200433

投稿日期:2003-08-16 修回日期:2003-01-05 发布日期:2014-02-17
通讯作者: 赵东元,E-mail:dyzhao@fudan.edu.cn E-mail:dyzhao@fudan.edu.cn
基金资助:
国家自然科学基金(Nos.20233030,20241004)和上海教育委员会"曙光"基金(No.02SG01)资助项目.

Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF(NDC=2,6-Naphthalenedicarboxylate)

ZHOU Guo-Qiang, CHEN Jin-Xi, CHEN Zhen-Xia, TIAN Yun-Qi, YU Ting, WENG Lin-Hong, ZHAO Dong-Yuan

Molecular Catalysis and Innovative Materials Laboratory, Department of Chemistry, Fudan University, Shanghai 200433

Received:2003-08-16 Revised:2003-01-05 Published:2014-02-17

Abstract

A new coordination polymer [Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF (1) has been synthesized by the reaction of MnCl₂·4H₂O with 2,6-naphthalenedicarboxylic acids (H₂NDC) under ambient conditions in DMF.A single crystal X-ray diffraction measurement reveals that 1 crystallized in the orthorhombic space group Pbca with a=1.8334(2) nm, b=1.6046(17) nm, c=2 .3706(3) nm, V=6.974(13) nm³, Z=8, D_c=1.471 g/cm³, M_r=772.50, μ=0.790 mm^-1 , F (000)=3176, S=0 .951, ( Δ/σ )_max=0.001, Δρ_max=0 .539, Δρ_min=-0.351, R=0.0335, wR=0.0859.The combination of octahedral manganese(Ⅱ) ions and NDC ligands leads to the formation of infinite three dimensional (3D) networks, which have lozenge-shaped 1D channels (0.7 nm×1 .2 nm) along the crystallographic b-axis.The cavities are filled with coordinated solvent molecules (DMF) and non coordinated ones.

Key words: coordination polymer, three-dimensional network, crystal structure

Cite this article

ZHOU Guo-Qiang, CHEN Jin-Xi, CHEN Zhen-Xia, TIAN Yun-Qi, YU Ting, WENG Lin-Hong, ZHAO Dong-Yuan. Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF(NDC=2,6-Naphthalenedicarboxylate)[J]. Acta Chimica Sinica, 2004, 62(9): 901-904.

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新型三维锰(Ⅱ)配位聚合物[Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF(NDC=2,6-萘二酸)的合成与表征

Synthesis and Characterization of a New 3D Manganese(Ⅱ) Coordination Polymer [Mn₂(NDC)₂(DMF)₂(H₂O)]_n·nDMF(NDC=2,6-Naphthalenedicarboxylate)

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新型三维锰(Ⅱ)配位聚合物[Mn2(NDC)2(DMF)2(H2O)]n·nDMF(NDC=2,6-萘二酸)的合成与表征