Synthesis,Structure and Thermal Stability of Metal Complexes with N, N-Dibenzyl Dithiocarbamate

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (17): 1626-1634. Previous Articles Next Articles

N,N-二苄基二硫代氨基甲酸金属配合物的合成、晶体结构及其热稳定性研究

范军¹, 殷霞¹, 章伟光¹, 张启交¹, Lai Chian-Sing², Tiekink Edward R. T.², 范毅³, 黄庙由³

1. 华南师范大学化学系, 广州, 510631;
2. 新加坡国立大学化学系, 新加坡, 117543;
3. 华南理工大学高分子材料科学与工程系, 广州, 510641

投稿日期:2004-01-12 修回日期:2004-03-23 发布日期:2014-02-17
通讯作者: wgzhang@scnu.edu.cn
作者简介:章伟光E-mail:wgzhang@scnu.edu.cn
基金资助:
广东省自然科学基金(No.990463),广东省教育厅自然科学基金(No.1999-89)和新加坡国立大学(No.R-143-000-213-112)资助项目.

Synthesis,Structure and Thermal Stability of Metal Complexes with N, N-Dibenzyl Dithiocarbamate

FAN Jun¹, YIN Xia¹, ZHANG Wei-Guang¹, ZHANG Qi-Jiao¹, LAI Chian-Sing², TIEKINK E. R. T.², FAN Yi³, HUANG Miao-You³

1. Department of Chemistry, South China Normal University, Guangzhou 510631, China;
2. Department of Chemistry, National University of Singapore, Singapore 117543, Singapore;
3. Department of Polymer Material and Science, South China University of Technology, Guangzhou 510641, China

Received:2004-01-12 Revised:2004-03-23 Published:2014-02-17

Abstract

Four metal complexes, which were shown as [Cd(DBTC)₂]₂ (1), [Hg(DBTC)₂] (2), [Nd(DBTC)₃·2H₂O] and [Nd(DBTC)₃(HMPA)₂] (3) (where DBTC=N,N-dibenzyl dithiocarbamate, HMPA=hexamethylphosphoramide), were synthesized and characterized by IR spectra.The structures of complexes 1～3 were determined by X-ray crystallography analysis.Crystal data of compound 1: C₃0H₂₈N₂CdS₄, M_r=657.18, monoclinic, space group P2 1/n, a=1.11098(4) nm, b=1.56325(5) nm, c=1.66695(5) nm, β=97.9220(10)°, Z=4, R=0.044, wR₁=0.091.Crystal data of compound 2: C₂0H₂₈N₂HgS₄, M_r=745.37, orthorhombic, space group Pbcn, a=1.64738(1) nm, b=1.86418(14) nm, c=0.94000(6) nm, Z=4, R=0.0387, wR₁=0.0965.Crystal data of compound 3: C₅₇H₇₈N₉NdO₂P₂S₆, M_r=1319.82, monoclinic, space group P2 1/c, a=1.30389(9) nm, b=3 4708(3) nm, c=3.1210(2) nm, β=96.527(2)°, Z=8, R=0.1023, WR₁=0.2203.Compound 1 is a dimer, and the Cd(Ⅱ) ion has an approximate tetragonal pyramidal geometry.Compounds 2 and 3 are monomers and show different coordination polyhedron.The Hg(Ⅱ) ion has a distorted tetrahedral coordination polyhedron, while the Nd(Ⅲ) ion exhibits distorted dodecahedral geometry.Thermal gravity (TG) data indicate that compounds 1 and 2 may be sublimed and decomposed in the course of heating and they might be expected to be useful precursors for MOCVD.

Key words: dithiocarbamate, complex, crystal structure, synthesis, thermal stability

Cite this article

FAN Jun, YIN Xia, ZHANG Wei-Guang, ZHANG Qi-Jiao, LAI Chian-Sing, TIEKINK E. R. T., FAN Yi, HUANG Miao-You. Synthesis,Structure and Thermal Stability of Metal Complexes with N, N-Dibenzyl Dithiocarbamate[J]. Acta Chimica Sinica, 2004, 62(17): 1626-1634.

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N,N-二苄基二硫代氨基甲酸金属配合物的合成、晶体结构及其热稳定性研究

Synthesis,Structure and Thermal Stability of Metal Complexes with N, N-Dibenzyl Dithiocarbamate

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