Recent Advances on Transition-Metal-Catalyzed Halogenation of Unactivated C-H Bonds

doi:10.6023/A15040295

Abstract

Halogenation is one of the most important reactions in organic synthesis. Recently, transition-mental-catalyzed C-H halogenation has emerged as a powerful and economical strategy for the synthesis of organohalides. In this review, we summarize recent advances on transition-metal-catalyzed halogenation of unactivated C-H bonds, according to the types of transition metals(palladium, copper, rhodium, ruthenium, and cobalt), the scope of reactions and mechanism. Finally, the limitations and perspectives on C-H halogenation are also described.

Key words: transition-metal, C-H activation, halogenation, organohalides

Cite this article

Liao Gang, Shi Bingfeng. Recent Advances on Transition-Metal-Catalyzed Halogenation of Unactivated C-H Bonds[J]. Acta Chimica Sinica, 2015, 73(12): 1283-1293.

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