Research Progress of Synthesis Methods for Crystalline Porous Materials

doi:10.6023/A22100442

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (2): 146-157.DOI: 10.6023/A22100442 Previous Articles Next Articles

Review

晶态多孔材料合成方法的研究进展

陈俊畅, 张明星, 王殳凹^*()

苏州大学放射医学与辐射防护国家重点实验室放射医学及交叉研究院(RAD-X) 江苏省高等学校医学协同创新中心苏州 215123

投稿日期:2022-10-31 发布日期:2022-12-05
通讯作者: 王殳凹

作者简介:

陈俊畅, 本科毕业于南华大学, 目前为苏州大学放射医学与防护学院博士研究生, 导师王殳凹教授, 研究方向为辐射化学合成功能材料及核技术应用研究.

张明星, 本科毕业于兰州大学, 2021年于中国科学院大学获博士学位, 目前为苏州大学放射医学与防护学院博士后, 主要研究方向为辐射法制备功能材料.

王殳凹教授, 苏州大学放射医学与防护学院副院长、放射医学与辐射防护国家重点实验室放射化学研究中心主任、教育部长江学者特聘教授、基金委杰出青年基金获得者. 2007年在中国科学技术大学获理学学士学位, 2012年在美国圣母大学获得博士学位, 2012~2013年在美国劳伦斯伯克利国家实验室和加州大学伯克利分校开展博士后研究. 现从事面向我国核能可持续发展及核安全重大需求的放射化学与辐射化学研究, 为我国乏燃料后处理、高放废物地质处置、核事故应急等重要任务提供了新思路. 近五年作为通讯作者在Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、CCS Chemistry等国际期刊上发表论文200余篇, 总引用11000余次. 曾获中国青年五四奖章和中国青年科技奖等荣誉.

基金资助:
国家重点研发计划(2021YFB3200400); 国家自然科学基金(21825601); 国家自然科学基金(21790374); 国家博士后创新人才支持计划(BX20220223); 中国博士后科学基金(2022M710103); 江苏省卓越博士后计划(2022ZB588)

Research Progress of Synthesis Methods for Crystalline Porous Materials

Junchang Chen, Mingxing Zhang, Shuao Wang()

State Key Laboratory of Radiation Medicine and Protection, School for Radiological and Interdisciplinary Sciences (RAD-X) and Collaborative Innovation Center of Radiation Medicine of Jiangsu Higher Education Institutions, Soochow University, Suzhou 215123, China

Received:2022-10-31 Published:2022-12-05
Contact: Shuao Wang
Supported by:
National Key Research and Development Program of China(2021YFB3200400); National Natural Science Foundation of China(21825601); the National Natural Science Foundation of China(21790374); fellowship of China National Postdoctoral Program for Innovative Talents(BX20220223); fellowship of China Postdoctoral Science Foundation(2022M710103); Jiangsu Postdoctoral Program for Excellence(2022ZB588)

Crystalline porous materials are a class of functional materials with high porosity, diverse structures, and controllable functions, which have broad application prospects in the adsorption and separation of guest molecules, catalysis, energy storage, and many other fields. Among these, zeolites, metal-organic frameworks (MOFs), and covalent organic frameworks (COFs) are most representative ones. With the continuous deepening research on porous materials, many novel synthesis methods have been explored for the basic research of materials. The development of crystalline porous materials synthesis methodologies is also related to their industrial applications. This review mainly focuses on the various synthesis methods for crystalline porous materials, and provides an overview of the synthesis methods of crystalline porous materials.

Key words: crystalline porous material, zeolites, metal-organic frameworks, covalent organic frameworks, synthesis methodology

Cite this article

Junchang Chen, Mingxing Zhang, Shuao Wang. Research Progress of Synthesis Methods for Crystalline Porous Materials[J]. Acta Chimica Sinica, 2023, 81(2): 146-157.

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Fig. & Tab. 4

Figure 1. Schematic diagram of the mechanical milling synthesis of S-Si-ZSM-5[68] (a), UiO-MOFs[76] (b) and β-ketoamine COFs[81] (c)

Figure 2. Schematic diagram of the sonochemical synthesis of ZSM-5[83] (a), ZIF-8[89] (b) and COFs[92] (c)

Figure 3. Schematic diagram of the electrochemical synthesis of Zr-UiO-66[118] (a) and COFs films[120] (b)

Figure 4. The synthesis schematic diagram of COFs[125] (a), Na-A[126] (b) and ZIFs[127] (c) through electron beam irradiation

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晶态多孔材料合成方法的研究进展

Research Progress of Synthesis Methods for Crystalline Porous Materials

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