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有机化学
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有机化学 ›› 2002, Vol. 22 ›› Issue (2): 141-144. 上一篇    下一篇

研究论文

水溶性的反式-二苯二乙烯基苯型非线性光学材料的合成

李仲辉;夏萍芳;孙康;黄文成   

  1. 四川教育学院化学系,成都(610041);香港浸会大学化学系香港九龙塘
  • 发布日期:2002-02-25

Synthesis of water-soluble optically nonlinear materials based on trans-Distyrylbenzene

Li Zhonghui;Xia Pingfang;Sun Kang;Wong Manshing   

  1. Department of Chemistry, Sichuan College of Education,Chengdu (610041);Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong
  • Published:2002-02-25

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被引次数

26 | 1

由3，4，5-三羟基苯甲酸甲酯经烷基化、还原、氧化和高度立体选择性的 Wadsworth-Emmons反应，合成了两个带六条烷氧基长链的水溶性的反式-二苯二乙 烯基苯(1a)和(1b)，经~1H NMR、MS及元素分析确证其结构。

关键词: 二乙烯基苯;合成;水溶性;非线性光学;表征;烷基化;还原;氧化, 核磁共振;质谱;元素分析

The 1,4-bis{trans-3,4,5-tri-[2-(2-methoxyethoxy) ethoxy] styryl} benzene (1a) and 1,4-bis {trans-3,4,5-tri-[2-(2-butoxyethoxy) ethoxy] styryl} benzene (1b) of water-soluble optically nonlinear materials have been synthesized by the highly stereoselective Wadsworth-Emmons reaction of the bis-phosphonate with the corresponding 3,4,5- trihydroxybenzaldehydes (2a) and 2b, respectively. The aldehyde 2 was prepared by the alkylation, reduction and oxidation of methyl 3,4,5- trihydroxybenzoate (5). The bis-phosphonate was prepared by the Michaelis-Arbuzov reaction using α, α'-dibromo-p-xylene and triethyl phosphite. All the new compounds were fully characterized with standard spectroscopic techniques.

Key words: DIETHENYLBENZENE;SYNTHESIS;WATER SOLUBILITY;NON LINEAR OPTICS, CHARACTERIZATION;ALKYLATION;REDUCTION;OXIDATION, NUCLEAR MAGNETIC RESONANCE;MASS SPECTRA;ELEMENTAL ANALYSIS

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