基于[PNP]配体的铬催化剂体系选择性催化乙烯齐聚的研究进展

doi:10.6023/cjoc201504009

有机化学 ›› 2015, Vol. 35 ›› Issue (9): 1861-1888.DOI: 10.6023/cjoc201504009 上一篇下一篇

综述与进展

基于[PNP]配体的铬催化剂体系选择性催化乙烯齐聚的研究进展

刘睿^a, 肖树萌^b, 钟向宏^b, 曹育才^c, 梁胜彪^b, 刘振宇^b, 叶晓峰^c, 沈安^c, 朱红平^a

a 厦门大学化学化工学院固体表面物理化学国家重点实验室厦门 361005;
b 中国石油化工股份有限公司茂名分公司茂名 525021;
c 上海化工研究院上海市聚烯烃催化技术重点实验室上海 200062

收稿日期:2015-04-08 修回日期:2015-05-19 发布日期:2015-05-26
通讯作者: 钟向宏, 朱红平 E-mail:zhonnogxh.mmsh@sipec.com;hpzhu@xmu.edu.cn
基金资助:
聚烯烃催化技术重点实验室基金(No. 12DZ2260400)、国家自然科学基金(No. 21473142)和教育部创新团队(No. IRT_14R31)资助项目.

Advances in Selective Ethylene Oligomerization Based on [PNP]-Ligand Chromium Catalysts

Liu Rui^a, Xiao Shumeng^b, Zhong Xianghong^b, Cao Yucai^c, Liang Shengbiao^b, Liu Zhenyu^b, Ye Xiaofeng^c, Shen An^c, Zhu Hongping^a

a State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005;
b Maoming Branch R&D Institute, SINOPEC, Maoming 525011;
c Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai Research Institute of Chemical Industry, Shanghai 200062

Received:2015-04-08 Revised:2015-05-19 Published:2015-05-26
Supported by:
Project Supported by the Key Laboratory of Catalysis Technology for Polyolefins (No. 12DZ2260400), the National Natural Science Foundation of China (No. 21473142), and the Program for Innovative Research Team in Chinese Universities (No. IRT_14R31).

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摘要/Abstract

乙烯选择性三聚和四聚催化反应为制备1-己烯和1-辛烯提供了重要途径. 在报道和披露的众多结构和组成的催化剂体系中, 我们选择[PNP]配位骨架的铬催化剂体系, 对其发展和应用进行了综述. 论文以结构与催化性能的关联性为主线, 阐述[PNP]骨架以及N和P上取代基的电子和立体空间效应对催化性能的影响. 从目前的研究态势来看, [PNP]配位骨架的铬催化剂体系在乙烯选择性齐聚生产1-辛烯等线性α-烯烃方面具有发展潜力.

关键词: 乙烯选择性齐聚, [PNP]配体, 铬催化剂, 1-己烯, 1-辛烯, 催化机理

The catalytic reaction for the selective ethylene trimerization and tetramerization provides a vital route to the production of 1-hexene and 1-octene. Among the numerous catalysts reported with diverse structures and compositions, we select the [PNP]-ligand based chromium catalysts and focus on illustration on their development and application. This contribution includes seven sections as ethylene (selective) oligomerization catalyst systems, [PNP]-ligand based Cr catalyst system, catalytic mechanism, ethylene oligomerization method, catalytic property, and conclusion and prospect, which will cover almost all of the [PNP]-ligand based Cr catalysts so far studied. In this article, we will mainly discuss the influence on the catalytic property owing to the electronic and/or steric characters of the skeleton as well as the substituents at both N and P atoms of the [PNP]-ligands. In view of the current advances in this field, this [PNP]-ligand based Cr catalyst system is of potencial in application for the production of LAO mainly as 1-octene.

Key words: selective ethylene oligomerization, [PNP] ligand, chromium catalyst, 1-hexene, 1-octene, catalytic mechanism

引用此文

刘睿, 肖树萌, 钟向宏, 曹育才, 梁胜彪, 刘振宇, 叶晓峰, 沈安, 朱红平. 基于[PNP]配体的铬催化剂体系选择性催化乙烯齐聚的研究进展[J]. 有机化学, 2015, 35(9): 1861-1888.

Liu Rui, Xiao Shumeng, Zhong Xianghong, Cao Yucai, Liang Shengbiao, Liu Zhenyu, Ye Xiaofeng, Shen An, Zhu Hongping. Advances in Selective Ethylene Oligomerization Based on [PNP]-Ligand Chromium Catalysts[J]. Chin. J. Org. Chem., 2015, 35(9): 1861-1888.

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基于[PNP]配体的铬催化剂体系选择性催化乙烯齐聚的研究进展

Advances in Selective Ethylene Oligomerization Based on [PNP]-Ligand Chromium Catalysts

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