有机化学 ›› 2015, Vol. 35 ›› Issue (9): 1848-1860.DOI: 10.6023/cjoc201504039 上一篇    下一篇

综述与进展

碘促进的砜基化反应研究进展

胡飞, 高文超, 常宏宏, 李兴, 魏文珑   

  1. 太原理工大学化学化工学院 生物与制药工程系 太原 030024
  • 收稿日期:2015-04-27 修回日期:2015-05-26 发布日期:2015-06-04
  • 通讯作者: 高文超, 常宏宏 E-mail:gaowenchao@tyut.edu.cn;changhonghong@tyut.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21206103)、太原理工大学青年基金(No. 2014QN011)资助项目.

Progress in Iodine-Mediated Sulfonylation Reactions

Hu Fei, Gao Wenchao, Chang Honghong, Li Xing, Wei Wenlong   

  1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024
  • Received:2015-04-27 Revised:2015-05-26 Published:2015-06-04
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21206103) and the Special/Youth Foundation of Taiyuan University of Technology (2014QN011).

近些年来, 利用亚磺酸盐或者磺酰肼为砜基源, 在含碘试剂的促进下完成的砜基化反应取得了很大进展. 按照砜基化的反应位点不同, 分类总结了利用各种含碘试剂引入砜基官能团的反应.

关键词: 碘, 亚磺酸盐, 砜基化, 无金属催化

With sulfites or sulfonyl hydrazides as the sulfonyl source, sulfonylation mediated by iodine-containing reagents has achieved much progress in recent years. According to different positions of sulfonylation, the progress involved the introduction of sulfonyl group mediated by various iodine-containing reagents is summarized.

Key words: iodine, sulfite, sulfonylation, metal-free catalysis